Publications

2024

445. Photoexcited Nickel-Catalyzed Carbohalogenation
Ramon Arora and Mark Lautens ACS Catal. 2024, ASAP, ASAP-ASAP. DOI: 10.1021/acscatal.3c05994 .


2023

444. Rapid Assembly of Unsymmetrically Linked Bis-heterocycles via Palladium Domino Catalysis
Ramon Arora, Jonathan Bajohr, and Mark Lautens Org. Lett. 2023, 25, 9053-9057. DOI: 10.1021/acs.orglett.3c03825 .


443. Palladium-Catalyzed Synthesis of Linked Bis-Heterocycles─Synthesis and Investigation of Photophysical Properties
Ramon Arora, Bijan Mirabi, Andrew G. Durant, Carlota Bozal-Ginesta, Austin D. Marchese, Alán Aspuru-Guzik, and Mark Lautens J. Am. Chem. Soc. 2023, 145, 26623-26631. DOI: 10.1021/jacs.3c07234 .


442. Nickel-Catalyzed sp3 C–H Activation
Colton E. Johnson, Shangyu Li, Ramon Arora, Bijan Mirabi, and Mark Lautens Synlett 2023, ASAP, ASAP-ASAP. DOI: 10.1055/s-0042-1751519 .


441. Stereoselective Kinugasa/Aldol Cyclization: Synthesis of Enantioenriched Spirocyclic β-Lactams
Alexa Torelli, Eun Seo Choi, Aurélien Dupeux, Marcel Nicolas Perner, and Mark Lautens Org. Lett. 2023, 25, 8520-8525. DOI: 10.1021/acs.orglett.3c03534 .


440. Discovery and Characterization of a Chemical Probe Targeting the Zinc-Finger Ubiquitin-Binding Domain of HDAC6
Rachel J. Harding, Ivan Franzoni, Mandeep K. Mann, Magdalena M. Szewczyk, Bijan Mirabi, Renato Ferreira de Freitas, Dominic D. G. Owens, Suzanne Ackloo, Alexej Scheremetjew, Kevin A. Juarez-Ornelas, Randy Sanichar, Rachel J. Baker, Christian Dank, Peter J. Brown, Dalia Barsyte-Lovejoy, Vijayaratnam Santhakumar, Matthieu Schapira, Mark Lautens, and Cheryl H. Arrowsmith J. Med. Chem. 2023, 66, 10274-10288. DOI: 10.1021/acs.jmedchem.3c00314 .


439. Pd-Catalyzed Domino Narasaka–Heck/C–H Activation/Amination Reactions: Synthesis of Bis-heterocyclic Spirocycles
Jonathan Bajohr, Aurélien Dupeux, Daniel Schenk, Clara Jans, and Mark Lautens Org. Lett. 2023, 25, 5361-5365. DOI: 10.1021/acs.orglett.3c01941 .


438. Photo-Uncaging by C(sp3)–C(sp3) Bond Cleavage Restores β-Lapachone Activity
Esther G. Kaye, Bijan Mirabi, Ivonne R. Lopez-Miranda, Komadhie C. Dissanayake, Upasana Banerjee, Madelyn Austin, Mark Lautens, Arthur H. Winter, Andrew A. Beharry J. Am. Chem. Soc. 2023, 145, 12518-12531. DOI: 10.1021/jacs.3c00398 .


437. Selective control of parasitic nematodes using bioactivated nematicides
Andrew R. Burns, Rachel J. Baker, Megan Kitner, Jessica Knox, Brittany Cooke, Jonathan R. Volpatti, Aditya S. Vaidya, Emily Puumala, Bruna M. Palmeira, Elizabeth M. Redman, Jamie Snider, Sagar Marwah, Sai W. Chung, Margaret H. MacDonald, Jens Tiefenbach, Chun Hu, Qi Xiao, Constance A. M. Finney, Henry M. Krause, Sonya A. MacParland, Igor Stagljar, John S. Gilleard, Leah E. Cowen, Susan L. F. Meyer, Sean R. Cutler, James J. Dowling, Mark Lautens, Inga Zasada, Peter J. Roy Nature 2023, 618, 102-109. DOI: 10.1038/s41586-023-06105-5 .

436. BF3-Catalyzed Intramolecular Fluorocarbamoylation of Alkynes via Halide Recycling
E. Ali McKnight, Ramon Arora, Ekadashi Pradhan, Yuriko H. Fujisato, Ayonitemi J. Ajayi, Mark Lautens, Tao Zeng, Christine M. Le J. Am. Chem. Soc. 2023, 145, 11012-11018. DOI: 10.1021/jacs.3c03982 .


435. Flipping the Switch on Palladium-Catalyzed Carboiodination: Accessing Kinetic and Thermodynamic Products
Ramon Arora, Regina M. Oechsner, Clara Jans, Bijan Mirabi, Austin D. Marchese, Mark Lautens ACS Catal. 2023, 13, 6562-6567. DOI: 10.1021/acscatal.3c01055 .


434. Synthesis of Spirooxindoles via Formal Acetylene Insertion into a Common Palladacycle Intermediate
Xavier Abel-Snape, Colton E. Johnson, Bianca Imbriaco, Mark Lautens Chem. Sci. 2023, 14, 5650-5655. DOI: 10.1039/D3SC01072D .


433. Nemacol is a small molecule inhibitor of C. elegans vesicular acetylcholine transporter with anthelmintic potential
Sean Harrington, Jacob Pyche, Andrew R. Burns, Tina Spalholz, Kaetlyn T. Ryan, Rachel J. Baker, Justin Ching, Lucien Rufener, Mark Lautens, Daniel Kulke, Alexandre Vernudachi, Mostafa Zamanian, Winnie Duether-Conrad, Peter Brust, Peter J. Roy Nat. Comm. 2023, 14, 1816-1816 . DOI: 10.1038/s41467-023-37452-6 .

432. Recent Developments of Palladium- and Rhodium-Catalyzed β-Carbon Elimination Strategies
Austin D. Marchese, Bijan Mirabi, Mark Lautens Synthesis 2023, 55, 2285-2303. DOI: 10.1055/a-2017-4868 .


431. Synthetic Ionizable Colloidal Drug Aggregates Enable Endosomal Disruption
Eric N. Donders, Kai V. Slaughter, Christian Dank, Ahil N. Ganesh, Brian K. Shoichet, Mark Lautens, Molly S. Shoichet Adv. Sci. 2023, 10, 2300311-2300311. DOI: 10.1002/advs.202300311 .

2022

430. (4+1), (4+3) and (4+4) Cycloadditions and Annulations
Heather Lam, Xavier Abel-Snape, Martin Köllen, and Mark Lautens Reference Module in Chemistry, Molecular Sciences and Chemical Engineering 2022, 66, 10274-10288. DOI: 10.1016/B978-0-32-390644-9.00048-2 .

429. Pd/Rh Dual Catalysis: Tandem Isomerization−Allylation to Access α‑Quaternary Carbonyl Compounds
Jeanne Masson-Makdissi, Justin Ching, Cian. M. Reid, Mark Lautens ACS Catal. 2022, 12, 15130-15134. DOI: 10.1021/acscatal.2c04818 .


428. Copper hydride catalysis enables facile access to fluorinated α-chiral tertiary trialkylamines
Bijan Mirabi, Austin D. Marchese, Mark Lautens Chem. Catal 2022, 2, 2802-2804. DOI: 10.1016/j.checat.2022.10.022 .

427. Pd(0)/Blue Light Promoted Carboiodination Reaction - Evidence for Reversible C-I Bond Formation via a Radical Pathway
Austin D. Marchese, Andrew G. Durant, Cian M. Reid, Clara Jans, Ramon Arora, Mark Lautens J. Am. Chem. Soc. 2022, 144, 20554-20560. DOI: 10.1021/jacs.2c09716 .


426. Rhodium(I)-Catalyzed Formate-Mediated Domino Heck/1,4-Hydride Addition toward Oxindoles
Egor M. Larin, Jeanne Masson-Makdissi, Young Jin Jang, Mark Lautens ACS Catal. 2022, 12, 12744-12749. DOI: 10.1021/acscatal.2c04128.


425. Egg-laying and locomotory screens with C. elegans yield a nematode-selective small molecule stimulator of neurotransmitter release
Sean Harrington, Jessica J. Knox, Andrew R. Burns, Ken-Loon Choo, Aaron Au, Megan Kitner, Cecile Haeberli, Jacob Pyche, Cassandra D'Amata, Yong-Hyun Kim, Jonathan R. Volpatti, Maximillano Guiliani, Jamie Snider, Victoria Wong, Bruna M. Palmeira, Elizabeth M. Redman, Aditya S. Vaidya, John S. Gilleard, Igor Stagljar, Sean R. Cutler, Daniel Kulke, James J. Dowling, Christopher M. Yip, Jennifer Keiser, Inga Zasada, Mark Lautens, Peter J. Roy Commun. Biol. 2022, 5, 865-879. DOI: 10.1038/s42003-022-03819-6 .

424. Palladium-Catalyzed Three-Component Dearomatization/Sulfonylation Cascade
Jonathan Bajohr, Matthias Bohme, Jiacheng Gao, F. Ekkehardt Hahn, Mark Lautens Org. Lett. 2022, 24, 3823-3827. DOI: 10.1021/acs.orglett.2c01382 .


423. Reversble C-C Bond Formation Using Palladium Catalysis
Austin D. Marchese, Bijan Mirabi, Colton E. Johnson, Mark Lautens Nat. Chem. 2022, 14, 398-406. DOI: 10.1038/s41557-022-00898-0 .


422. Dual Ni/Organophotoredox Catalyzed Allylative Ring Opening Reaction of Oxabenzonorbornadienes and Analogs
Abdoul G. Diallo, Déborah Paris, Djiby Faye, Sylvain Gaillard, Mark Lautens, and Jean-Luc Renaud ACS Catal. 2022, 12, 3681-3688. DOI: 10.1021/acscatal.2c00512 .


421. Synthesis of Indenes and Benzofulvenes via a Palladium-Catalyzed Three-Component Reaction
Xavier Abel-Snape, Gina Wycich, Mark Lautens ACS Catal. 2022, 12, 3291-3301. DOI: 10.1021/acscatal.1c06046 .


420. A Modular Approach for the Palladium-Catalyzed Synthesis of Bis-heterocyclic Spirocycles
Austin D. Marchese, Andrew G. Durant, Mark Lautens Org. Lett. 2022, 24, 95-99. DOI: 10.1021/acs.orglett.1c03682 .


2021

419. Dearomative Cyclopropanation of Naphthols via Cyclopropene Ring-Opening
Rachel J. Baker, Justin Ching, Teh Ren Hou, Ivan Franzoni, Mark Lautens Angew. Chem. Int. Ed. 2021, 61, e202116171-e202116171. DOI: 10.1002/anie.202116171 .


418. Accessing Unsymmetrically Linked Heterocycles through Stereoselective Palladium-Catalyzed Domino Cyclization
Ramon Arora, Jose F. Rodriguez, Andrew Whyte, Mark Lautens Angew. Chem. Int. Ed. 2021, 61, e202112288-e202112288. DOI: 10.1002/anie.202112288 .


417. Nickel-Catalyzed Reductive Cross-Coupling of Heteroaryl Chlorides and Aryl Chlorides
Bijan Mirabi, Austin D. Marchese, Mark Lautens ACS Catal. 2021, 11, 12785-12793. DOI: 10.1021/acscatal.1c02307 .


416. Synthesis of 1-Amino-2,2,2-trifluoroalkylphosphonates from Alkene-Tethered Trifluoroacetimidoyl Chlorides
Jose F. Rodriguez, Anji Zhang, Ramon Arora, Mark Lautens Org. Lett. 2021, 23, 7540-7544. DOI: 10.1021/acs.orglett.1c02750 .


415. Sequential Pd(0)- and Pd(II)-Catalyzed Cyclizations: Enantioselective Heck and Nucleopalladation Reactions
Andrew Whyte, Jonathan Bajohr, Ramon Arora, Alexa Torelli, Mark Lautens Angew. Chem. Int. Ed. 2021, 60, 20231-20236. DOI: 10.1002/anie.202106518 .


414. Iron-Catalyzed Reductive Cyclization by Hydromagnesiation: A Modular Strategy Towards N-Heterocycles
Joachim Loup, Egor M. Larin, Mark Lautens Angew. Chem. Int. Ed. 2021, 60, 22345-22351. DOI: 10.1002/anie.202106996 .


413. Enantioselective Synthesis of Spiro-oxiranes: An Asymmetric Addition/Aldol/Spirocyclization Domino Cascade
Ken-Loon Choo, Bijan Mirabi, Karl Z. Demmans, Mark Lautens Angew. Chem. Int. Ed. 2021, 60, 21189-21194. DOI: 10.1002/anie.202105562 .


412. Cycloisomerization of Carbamoyl Chlorides in Hexafluoroisopropanol: Stereoselective Synthesis of Chlorinated Methylene Oxindoles and Quinolinones
Jose F. Rodriguez, Anji Zhang, Jonathan Bajohr, Andrew Whyte, Bijan Mirabi, Mark Lautens Angew. Chem. Int. Ed. 2021, 60, 18478-18483. DOI: 10.1002/anie.202103323 .


411. Enantio- and Diastereodivergent Sequential Catalysis Featuring Two Transition Metal-Catalyzed Asymmetric Reactions
Jeanne Masson-Makdissi, Liher Prieto, Xavier Abel-Snape, Mark Lautens Angew. Chem. Int. Ed. 2021, 60, 16932-16936. DOI: 10.1002/anie.202105800 .


410. Recent Strategies for Carbon-Halogen Bond Formation Using Nickel
Austin D. Marchese, Timur Adrianov, Mark Lautens Angew. Chem. Int. Ed. 2021, 60, 16750-16762. DOI: 10.1002/anie.202101324 .


409. Palladium-Catalyzed Domino Heck/Sulfination: Synthesis of Sulfonylated Hetero- and Carbocyclic Scaffolds Using DABCO-Bis(sulfur dioxide)
Jonathan Bajohr, Abdoul G. Diallo, Andrew Whyte, Sylvain Gaillard, Jean-Luc Renaud, Mark Lautens Org. Lett. 2021, 23, 2797-2801. DOI: 10.1021/acs.orglett.1c00716 .


408. Recent Advances in Transition-Metal-Free (4+3)-Annulations
Heather Lam, Xavier Abel-Snape, Martin F. Köllen, Mark Lautens Synthesis 2021, 53, 4134-4177. DOI: 10.1055/s-0040-1706023 .


407. One-Pot, Three-Step Synthesis of Benzoxazinones via Use of the Bpin Group as a Masked Nucleophile
Egor M. Larin, Alexa Torelli, Joachim Loup, Mark Lautens Org. Lett. 2021, 23, 2720-2725. DOI: 10.1021/acs.orglett.1c00623 .


406. Catalytic Asymmetric Transformations of Oxa- and Azabicyclic Alkenes
Sundaravel Vivek Kumar, Andy Yen, Mark Lautens, Patrick J. Guiry Chem. Soc. Rev. 2021, 50, 3013-3093. DOI: 10.1039/D0CS00702A .


405. Synthesis of Carbocyclic Compounds via a Nickel-Catalyzed Carboiodination Reaction
Austin D. Marchese, Timur Adrianov, Martin F. Kollen, Bijan Mirabi, Mark Lautens ACS Catal. 2021, 11, 925-931. DOI: 10.1021/acscatal.0c04956 .


2020

404. Stereoselective Construction of y-Lactams via Copper-Catalyzed Borylacylation
Alexa Torelli, Andrew Whyte, Iuliia Polishchuk, Jonathan Bajohr, Mark Lautens Org. Lett. 2020, 22, 7915-7919. DOI: 10.1021/acs.orglett.0c02837 .


403. Synthesis of Aminated Phenanthridinones via Palladium/Norbornene Catalysis
Xavier Abel-Snape, Andrew Whyte, Mark Lautens Org. Lett. 2020, 22, 7920-7925. DOI: 10.1021/acs.orglett.0c02850 .


402. Copper-Catalyzed Borylative Difunctionalization of pi-Systems
Andrew Whyte, Alexa Torelli, Bijan Mirabi, Anji Zhang, Mark Lautens ACS Catal. 2020, 10, 11578-11622. DOI: 10.1021/acscatal.0c02758 .


401. Metal-Catalyzed Approaches toward the Oxindole Core
Austin D. Marchese, Egor M. Larin, Bijan Mirabi, Mark Lautens Acc. Chem. Res. 2020, 53, 1605-1619. DOI: 10.1021/acs.accounts.0c00297 .


400. Enantioselective Cobalt-Catalyzed Intermolecular Hydroacylation of 1,6-Enynes
Andrew Whyte, Jonathan Bajohr, Alexa Torelli, Mark Lautens Angew. Chem. Int. Ed. 2020, 59, 16409-16413. DOI: 10.1002/anie.202006716 .


399. Rhodium-Catalyzed Intermolecular Cyclopropanation of Benzofurans, Indoles, and Alkenes via Cyclopropene Ring Opening
Rachel J. Ross, Rubaishan Jeyaseelan, Mark Lautens Org. Lett. 2020, 22, 4838-4843. DOI: 10.1021/acs.orglett.0c01655 .


398. Enantio- and diastereoselective conjugate borylation/Mannich cyclization
Egor M. Larin, Joachim Loup, Iuliia Polishchuk, Rachel J. Ross, Andrew Whyte, Mark Lautens Chem. Sci. 2020, 11, 5716-5723. DOI: 10.1039/D0SC02421J .


397. Cobalt-Catalyzed Enantioselective Hydroarylation of 1,6-Enynes
Andrew Whyte, Alexa Torelli, Bijan Mirabi, Liher Prieto, Jose F. Rodriguez, Mark Lautens J. Am. Chem. Soc. 2020, 142, 9510-9517. DOI: 10.1021/jacs.0c03246 .


396. Palladium-Catalyzed Disilylation and Digermanylation of Alkene Tethered Aryl Halides: Direct Access to Versatile Silylated and Germanylated Heterocycles
Marco Wollenburg, Jonathan Bajohr, Austin D. Marchese, Andrew Whyte, Frank Glorius, Mark Lautens Org. Lett. 2020, 22, 3679-3683. DOI: 10.1021/acs.orglett.0c01169 .


395. Synthesis and Reactions of 3,3-Difluoro-2-exo-methylidene Indoline
Nicolas Zeidan, Matthew Zambri, Sven Unger, Christian Dank, Alexa Torelli, Bijan Mirabi, Mark Lautens Org. Lett. 2020, 22, 3688-3691. DOI: 10.1021/acs.orglett.0c01175 .


394. Recent Advances in Transition-Metal-Catalyzed (4+3)-Cycloadditions
Heather Lam, Mark Lautens Synthesis 2020, 52, 2427-2449. DOI: 10.1055/s-0039-1690875 .


393. Nickel-Catalyzed Enantioselective Carbamoyl Iodination: A Surrogate for Carbamoyl Iodides
Austin D. Marchese, Marco Wollenburg, Bijan Mirabi, Xavier Abel-Snape, Andrew Whyte, Frank Glorius, Mark Lautens ACS Catal. 2020, 10, 4780-4785. DOI: 10.1021/acscatal.0c00841 .


392. Aminomethylation of Oxabenzonorbornadienes via the Merger of Photoredox and Nickel Catalysis
Abdoul G. Diallo, David Roy, Sylvain Gaillard, Mark Lautens, Jean-Luc Renaud Org. Lett. 2020, 22, 2442-2447. DOI: 10.1021/acs.orglett.0c00593 .


2019

391. Rhodium–Catalyzed Tandem Isomerization–Allylation: From Diallyl Carbonates to a-Quaternary Aldehydes
Jeanne Masson-Makdissi, Young Jin Jang, Liher Prieto, Mark S. Taylor, Mark Lautens ACS Catal. 2019, 9, 11808-11818. DOI: 10.1021/acscatal.9b04128 .


390. Rhodium(I)/Zn(OTf)2–Catalyzed Asymmetric Ring Opening/Cyclopropanation of Oxabenzonorbornadienes with Phosphorus Ylides
Tao Chen, Lifei Gan, Ran Wang, Yuhua Deng, Fangzhi Peng, Mark Lautens, Zhihui Shao Angew. Chem. Int. Ed. 2019, 58, 15819-15823. DOI: 10.1002/anie.201909596 .


389. A Simplified Protocol for the Stereospecific Nickel-Catalyzed C–S Vinylation using NiX2 Salts and Alkyl Phosphites
Austin D. Marchese, Bijan Mirabi, Egor M. Larin, Mark Lautens Synthesis 2019, 52, 311-319. DOI: 10.1055/s-0039-1690717 .


388. The Emergence of Pd-mediated reversible oxidative addition in cross-coupling, carbohalogenation and carbonylation reactions.
David J. Jones, Mark Lautens, Gerard P. McGlacken Nature Catalysis 2019, 2, 843-851. DOI: 10.1038/s41929-019-0361-0 .

387. Enantioselective Copper-Catalyzed Borylative Cyclization with Cyclic Imides
Andrew Whyte, Alexa Torelli, Bijan Mirabi, Mark Lautens Org. Lett. 2019, 21, 8873-8377. DOI: 10.1021/acs.orglett.9b03144 .


386. Asymmetric Synthesis of Boryl-Functionalized Cyclobutanols
Andrew Whyte, Bijan Mirabi, Alexa Torelli, Liher Prieto, Jonathan Bajohr, Mark Lautens ACS Catal. 2019, 9, 9253-9258. DOI: 10.1021/acscatal.9b03216 .


385. Rhodium-Catalyzed Enantioselective Synthesis of Oxazinones via an Asymmetric Ring Opening-Lactonization Cascade of Oxabicyclic Alkenes
Andy Yen, Anh Hoang Pham, Egor M. Larin, Mark Lautens Org. Lett. 2019, 21, 7549-7533. DOI: 10.1021/acs.orglett.9b02819 .


384. Migratory Insertion Strategies for Dearomatization
Nicolas Zeidan, Mark Lautens Synthesis 2019, 51, 4137-4146. DOI: 10.1055/s-0037-1611918 .


383. Diastereoselective Nickel-Catalyzed Carboiodination Generating Six-Membered Nitrogen-Based Heterocycles
Austin D. Marchese, Louise Kersting, Mark Lautens Org. Lett. 2019, 21, 7163-7168. DOI: 10.1021/acs.orglett.9b02797 .


382. Recent Advances Towards Syntheses of Diterpenoid Alkaloids
Christian Dank, Randy Sanichar, Ken-Loon Choo, Madeline Olsen, Mark Lautens Synthesis 2019, 51, 3915-3946. DOI: 10.1055/s-0037-1611897 .


381. Intramolecular Copper(I)-Catalyzed Interrupted Click/Acylation Domino Reaction
Egor M. Larin, Mark Lautens Angew. Chem. Int. Ed. 2019, 58, 13438-13442. DOI: 10.1002/anie.201907448 .


380. Forming Benzylic Iodides via a Nickel Catalyzed Diastereoselective Dearomative Carboiodination Reaction of Indoles
Austin D. Marchese, Florian Lind, Áine E. Mahon, Hyung Yoon, Mark Lautens Angew. Chem. Int. Ed. 2019, 58, 5095-5099. DOI: 10.1002/anie.201900659 .


379. Tandem Remote Csp3–H Activation/Csp3–Csp3 Cleavage in Unstrained Aliphatic Chains Assisted by Palladium(II)
Marta Pérez-Gómez, Hamid Azizollahi, Ivan Franzoni , Egor M. Larin, Mark Lautens, and José-Antonio García-López Organometallics. 2019, 38, 973-980. DOI: 10.1021/acs.organomet.8b00920 .


378. Pd-catalyzed dearomative arylborylation of indoles
Chong Shen, Nicolas Zeidan, Quan Wu, Christian B. J. Breuers, Ren-Rong Liu, Yi-Xia Jia, Mark Lautens Chem. Sci. 2019, 10, 3118-3122. DOI: 10.1039/C8SC05737K .


377. Visible-Light-Mediated Deaminative Three-Component Dicarbofunctionalization of Styrenes with Benzylic Radicals
Felix J. R. Klauck, Hyung Yoon, Michael J. James, Mark Lautens, Frank Glorius ACS Catal. 2019, 9, 236-241. DOI: 10.1021/acscatal.8b04191 .


2018

376. Palladium-Catalyzed Arylation/Heteroarylation of Indoles: Access to 2,3-Functionalized Indolines
Nicolas Zeidan, Tamara Beisel, Rachel Ross, Mark Lautens Org. Lett. 2018, 20, 7332-7335. DOI: 10.1021/acs.orglett.8b03310 .


375. Transition Metal-Free [4+3]-Cycloaddition of ortho-Quinone Methides and Isomünchnones: Catalytic and Diastereoselective Assembly of Oxa-bridged Oxazocine Scaffolds
Heather Lam, Zafar Qureshi, Marcus Wegmann, Mark Lautens Angew. Chem. Int. Ed. 2018, 57, 16185-16189. DOI: 10.1002/anie.201810760 .


374. Rhodium-Catalyzed Enantioselective Defluorinative a-Arylation of Secondary Amides
Young Jin Jang, Daniel Rose, Bijan Mirabi, Mark Lautens Angew. Chem. Int. Ed. 2018, 57, 16147-16151. DOI: 10.1002/anie.201808509 .


373. Palladium-Catalyzed Hydride Addition/C–H Bond Activation Cascade: Cycloisomerization of 1,6-Diynes
José F. Rodríguez, Katherine I. Burton, Ivan Franzoni, David A. Petrone, Ina Scheipers, Mark Lautens Org. Lett. 2018, 20, 6915-6919. DOI: 10.1021/acs.orglett.8b03057 .


372. Enantioselective Intramolecular Copper-Catalyzed Borylacylation
Andrew Whyte, Katherine I. Burton, Dr. Jingli Zhang, Prof. Dr. Mark Lautens Angew. Chem. Int. Ed. 2018, 57, 13927-13930. DOI: 10.1002/anie.201808460 .


371. Carboiodination Catalyzed by Nickel
Hyung Yoon, Austin D. Marchese, Mark Lautens J. Am. Chem. Soc. 2018, 140, 10950-10954. DOI: 10.1021/jacs.8b06966 .


370. Palladium-Catalyzed Synthesis of Dihydrobenzoindolones via C–H Bond Activation and Alkyne Insertion
José F. Rodríguez, Austin D. Marchese, Mark Lautens Org. Lett. 2018, 20, 4367-4370. DOI: 10.1021/acs.orglett.8b01856 .


369. Nickel-Catalyzed Intramolecular Arylcyanation for the Synthesis of 3,3-Disubstituted Oxindoles
Andy Yen, Mark Lautens Org. Lett. 2018, 20, 4323-4327. DOI: 10.1021/acs.orglett.8b01772 .


368. Identification and Structure–Activity Relationship of HDAC6 Zinc-Finger Ubiquitin Binding Domain Inhibitors
Renato Ferreira de Freitas, Rachel J. Harding, Ivan Franzoni, Mani Ravichandran, Mandeep K. Mann, Hui Ouyang, Mark Lautens, Vijayaratnam Santhakumar, Cheryl H. Arrowsmith, Matthieu Schapira J. Med. Chem. 2018, 61, 4517-4527. DOI: 10.1021/acs.jmedchem.8b00258 .


367. Rhodium-Catalyzed Asymmetric Conjugate Alkynylation/Aldol Cyclization Cascade for the Formation of α-Propargyl-β-hydroxyketones
Ken-Loon Choo, Mark Lautens Org. Lett. 2018, 20, 1380-1383. DOI: 10.1021/acs.orglett.8b00153.


2017

366. Palladium-Catalyzed, Norbornene-Mediated, ortho-Amination ipso-Amidation: Sequential C–N Bond Formation
Andrew Whyte, Maxwell E. Olson, Mark Lautens Org. Lett. 2017, 2, 345-348. DOI: 10.1021/acs.orglett.7b03577 .


365. Exploring the mechanism of the Pd-catalyzed spirocyclization reaction: a combined DFT and experimental study
Ivan Franzoni, Hyung Yoon, Jose-Antonio Garcia Lopez, Amalia Isabel Poblador-Bahamonde, Mark Lautens Chem. Sci. 2017, 9, 1496-1509. DOI: 10.1039/C7SC04709F .


364. Synthesis and Reactivity of Model Intermediates Proposed for the Pd-Catalyzed Remote C–H Functionalization of N-(2-Haloaryl)acrylamides
Marta Perez-Gomez, Leticia Navarro, Isabel Saura-Llamas, Delia Bautista, Mark Lautens, José-Antonio García-López Organometallics. 2017, 36, 4465-4476. DOI: 10.1021/acs.organomet.7b00702 .


363. Guest Editorial: Celebrating Canadian Chemistry
Prof. Dr. Douglas W. Stephan, Prof. Dr. Mark Lautens Angew. Chem. Int. Ed. 2017, 56, 5948-5949. DOI: 10.1002/anie.201702437 .

362. Small molecule antagonists of the interaction between the histone deacetylase 6 zinc-finger domain and ubiquitin
Rachel J. Harding, Renato Ferreira de Freitas, Patrick Michael Collins, Ivan Franzoni, Mani Ravichandran, Hui Ouyang, Kevin A. Juarez-Ornelas, Mark Lautens, Matthieu Schapira, Frank von Delft, Vijayaratnam Santhakumar, and Cheryl H. Arrowsmith J. Med. Chem. 2017, 60, 9090-9096. DOI: 10.1021/acs.jmedchem.7b00933.


361. Palladium-Catalyzed Synthesis of 2-Cyanoindoles from 2-gem-Dihalovinylanilines
Nicolas Zeidan, Sabine Bognar, Sophia Lee, Mark Lautens Org. Lett. 2017, 19, 5058-5061. DOI: 10.1021/acs.orglett.7b02244 .


360. Rhodium-Catalyzed Enantioselective Reductive Arylation: Convenient Access to 3,3-Disubstituted Oxindoles
Young Jin Jang, Egor M. Larin and Prof. Dr. Mark Lautens Angew. Chem. Int. Ed. 2017, 56, 11927-11930. DOI: 10.1002/anie.201704922 .


359. Palladium-Catalyzed Spirocyclization through C–H Activation and Regioselective Alkyne Insertion
Hyung Yoon, Martin Rölz, Felicitas Landau and Prof. Dr. Mark Lautens Angew. Chem. Int. Ed. 2017, 56, 10920-10923. DOI: 10.1002/anie.201706325 .


358. Synthesis of Pyridobenzazepines Using a One-Pot Rh/Pd-Catalyzed Process
Heather Lam, Jennifer Tsoung, Mark Lautens J. Org. Chem. 2017, 82, 6089-6099. DOI: 10.1021/acs.joc.7b00568 .


357. Rhodium-Catalyzed Enantioselective Isomerization of meso-Oxabenzonorbornadienes to 1,2-Napthalene Oxides
Andy Yen, Ken Loon-Choo, Shabnam K. Yazdi, Dr. Patrick T. Franke, Dr. Robert Webster, Dr. Ivan Franzoni, Dr. Charles C.J. Loh, Dr. Amalia I. Poblador-Bahamonde, Prof. Dr. Mark Lautens Angew. Chem. Int. Ed. 2017, 56, 6307-6311. DOI: 10.1002/anie.201700632 .


356. Palladium-Catalyzed Hydrohalogenation of 1,6-Enynes: Hydrogen Halide Salts and Alkyl Halides as Convenient HX Surrogates
David A. Petrone, Ivan Franzoni, Juntao Ye, José F. Rodríguez, Amalia I. Poblador-Bahamonde, Mark Lautens J. Am. Chem. Soc. 2017, 139, 3546-3557. DOI: 10.1021/jacs.7b00482 .


355. Mechanistic insights on the Pd-catalyzed addition of C-X bonds across alkynes - a combined experimental and computational study
Theresa Sperger, Christine M. Le, Mark Lautens, Franziska Schoenebeck Chem. Sci. 2017, 8, 2914-2922. DOI: 10.1039/C6SC05001H .


354. Discovery and structure activity relationship of the first potent cryptosporidium FIKK kinase inhibitor
Khan T. Osman, Juntao Ye, Zhihao Shi, Christina Toker, Diogo Lovato, Rajiv S. Jumani, William Zuercher, Christopher D. Houston, Aled M. Edwards, Mark Lautens, Vijayaratnam Santhakumar, Raymond Hui Bioorg. Med. Chem. 2017, 25, 1672-1680. DOI: 10.1016/j.bmc.2017.01.036 .


353. Employing Pd-Catalyzed C-H Arylation in Multicomponent-Multicatalyst Reactions (MC)2R: One-Pot Synthesis of Dihydrobenzoquinolines
Fabian Lied, Helena Brodnik Zugelj, Steffen Kress, Bogdan Stefane, Frank Glorius, Mark Lautens ACS Catal. 2017, 7, 1378-1382. DOI: 10.1021/acscatal.6b03209 .


352. Secondary Alkyl Groups in Palladium-Catalyzed Cross-Coupling Reactions
Zafar Qureshi, Christina Toker, Mark Lautens Synthesis 2017, 49, 1-16. DOI: 10.1055/s-0035-1561625 .


351. Remote C-H Alkylation and C-C Bond Cleavage Enabled by an in situ Generated Palladacycle
Juntao Ye, Zhihao Shi, Theresa Sperger, Yoshifumi Yasukawa, Cian Kingston, Franziska Schoenebeck, Mark Lautens Nat. Chem. 2017, 9, 361-368. DOI: 10.1038/nchem.2631 .


2016

350. Palladium-Catalyzed Alpha-Arylation of Vinylogous Esters for the Synthesis of Gamma,Gamma-Disubstituted Cyclohexenones
Thomas Johnson, Felix Pultar, Friedericke Menke, Mark Lautens Org. Lett. 2016, 18, 6488-6491. DOI: 10.1021/acs.orglett.6b03394 .


349. Pd-Catalyzed Spirocyclization via C-H Activation and Benzyne Insertion
Hyung Yoon, Alexis Lossouarn, Felicitas Landau, Mark Lautens Org. Lett. 2016, 18, 6324-6327. DOI: 10.1021/acs.orglett.6b03213 .


348. Stereoselective Synthesis of Methylene Oxindoles via Palladium(II)-Catalyzed Intramolecular Cross-Coupling of Carbamoyl Chlorides
Christine M. Le, Theresa Sperger, Rui Fu, Xiao Hou, Yong Hwan Lim, Franziska Schoenebeck, Mark Lautens J. Am. Chem. Soc. 2016, 138, 14441-14448. DOI: 10.1021/jacs.6b08925 .


347. Expanding the Scope of the Gold(I)-Catalyzed Rautenstrauch Rearrangement: Protic Additives
Cedric Burki, Andrew Whyte, Sebastian Arndt, A. Stephen K. Hashmi, Mark Lautens, Org. Lett. 2016, 18, 5058-5061. DOI: 10.1021/acs.orglett.6b02505 .


346. Combining Ru-Catalyzed C-H Functionalization with Pd-Catalyzed Asymmetric Allylic Alkylation: Synthesis of 3-Allyl-3-aryl Oxindole Derivatives from Aryl Alpha-Diazoamides
Kosuke Yamamoto, Zafar Qureshi, Jennifer Tsoung, Guillaume Pisella, and Mark Lautens, Org. Lett. 2016, 18, 4954-4957. DOI: 10.1021/acs.orglett.6b02423 .


345. Palladium-Catalyzed Norbornene-Mediated Tandem Amination/Cyanation Reaction: A Method for the Synthesis of ortho-Aminated Benzonitriles
Bo Luo, Jin-Ming Gao, Mark Lautens Org. Lett. 2016, 18, 4166-4169. DOI: 10.1021/acs.orglett.6b02249 .


344. Rhodium-Catalyzed Asymmetric Cycloisomerization and Parallel Kinetic Resolution of Racemic Oxabicycles
Dr. Charles C.J. Loh, Matthias Schmid, Dr. Robert Webster, Andy Yen, Shabnam K. Yazdi, Dr. Patrick T. Franke, Prof. Dr. Mark Lautens Angew. Chem. Int. Ed. 2016, 55, 10074-10078. DOI: 10.1002/anie.201604937 .


343. Cu/Pd-Catalyzed Synthesis of Fully Decorated Polycyclic Triazoles: Introducing C–H Functionalization to Multicomponent Multicatalytic Reactions ((MC)2R)
Zafar Qureshi, Jung Yun Kim, Theodora Bruun, Heather Lam, and Mark Lautens, ACS Catal. 2016, 6, 4946-4952. DOI: 10.1021/acscatal.6b00858 .


342. Orthogonally Reacting Boron Coupling Reagents: A Novel Multicomponent-Multicatalytic Reaction [(MC)2R] of Dichlorovinylpyrazine
Jordan M. Rebelo, Steffen Kress, Adam, A. Friedman and Mark Lautens Synthesis 2016, 48, 3155-3164. DOI: 10.1055/s-0035-1561670 .


341. Modern Transition-Metal-Catalyzed Carbon–Halogen Bond Formation
David A. Petrone, Juntao Ye, and Mark Lautens Chem. Rev. 2016, 116, 8003-8104. DOI: 10.1021/acs.chemrev.6b00089 .


340. Palladium(II)-Catalyzed Enantioselective Synthesis of a-(Trifluoromethyl)arylmethylamines
Thomas Johnson, Bo Luo, and Mark Lautens J. Org. Chem. 2016, 81, 4923-4930. DOI: 10.1021/acs.joc.6b00657 .


339. A New Multicomponent Multicatalyst Reaction (MC)2R: Chemoselective Cycloaddition and Latent Catalyst Activation for the Synthesis of Fully Substituted 1,2,3-Triazoles
Kosuke Yamamoto, Theodora Bruun, Jung Yun Kim, Lei Zhang, and Mark Lautens Org. Lett. 2016, 18, 2644-2647. DOI: 10.1021/acs.orglett.6b00975 .


338. Diastereoselective Pd-Catalyzed Domino Heck/Arylborylation Sequence Forming Borylated Chromans
Hyung Yoon, Young Jin Jang, Mark Lautens Synthesis 2016, 48, 1483-1490. DOI: 10.1055/s-0035-1561567 .


337. Pd(0)-Catalyzed Dearomative Diarylation of Indoles
David A. Petrone, Masaru Kondo, Nicolas Zeidan and Prof. Dr. Mark Lautens Chem. Eur. J. 2016, 22, 5684-5691. DOI: 10.1002/chem.201600118 .


336. Exploiting Distal Reactivity of Coumarins: A Rhodium-Catalyzed Vinylogous Asymmetric Ring-Opening Reaction
Dr. Charles C. J. Loh, Matthias Schmid, Brendan Peters, Dr. Xiang Fang and Prof. Dr. Mark Lautens Angew. Chem. Int. Ed. 2016, 55, 4600-4604. DOI: 10.1002/anie.201600654 .


335. Synthetic and Mechanistic Studies on the Rhodium-Catalyzed Redox Isomerization of Cyclohexa-2,5-dienols
Steffen Kress, Thomas Johnson, Florian Weisshar, and Mark Lautens ACS Catal. 2016, 6, 747-750. DOI: 10.1021/acscatal.5b02387 .


2015

334. An Exclusively trans-Selective Chlorocarbamoylation of Alkynes Enabled by a Palladium/Phosphaadamantane Catalyst
Christine M. Le, Xiao Hou, Theresa Sperger, Prof. Dr. Franziska Schoenebeck and Prof. Dr. Mark Lautens Angew. Chem. Int. Ed. 2015, 54, 15897-15900. DOI: 10.1002/anie.201507883 .


333. Palladium-catalysed norbornene-mediated C–H functionalization of arenes
Juntao Ye and Mark Lautens Nature Chem. 2015, 7, 863-870. DOI: 10.1038/nchem.2372 .


332. Dearomative Indole Bisfunctionalization via a Diastereoselective Palladium-Catalyzed Arylcyanation
David A. Petrone, Andy Yen, Nicolas Zeidan, and Mark Lautens Org. Lett. 2015, 17, 4838-4841. DOI: 10.1021/acs.orglett.5b02403 .


331. Benzylic Functionalization of Anthrones via the Asymmetric Ring Opening of Oxabicycles Utilizing a Fourth-Generation Rhodium Catalytic System
Dr. Charles C. J. Loh, Dr. Xiang Fang, Brendan Peters and Prof. Dr. Mark Lautens Chem. Eur. J. 2015, 21, 13883-13887. DOI: 10.1002/chem.201502718 .


330. Rh-Catalyzed Domino Addition Enolate Arylation: Generation of 3-Substituted Oxindoles via a Rh(lll) Intermediate
Young Jin Jang, Hyung Yoon, and Mark Lautens Org. Lett. 2015, 17(15), 3895-3897. DOI: 10.1021/acs.orglett.5b01737 .


329. Introduction of Hindered Electrophiles via C-H Functionalization in a Palladium-Catalyzed Multicomponent Domino Reaction
Zafar Qureshi, Waldemar Schlundt, Mark Lautens Synthesis 2015, 47(16), 2446-2456. DOI: 10.1055/s-0034-1380198 .


328. Synthesis of Enantioenriched 5,6-Dihydrophenanthridine Derivatives through retro-Carbopalladation of Chiral o-Bromobenzylamines
Dr. Juntao Ye, Aurore Limouni, Sonia Zaichuk and Prof. Dr. Mark Lautens Angew. Chem. Int. Ed. 2015, 54, 3116-3120. DOI: 10.1002/anie.201411276 .


327. Synergistic Steric Effects in the Development of a Palladium-Catalyzed Alkyne Carbohalogenation: Stereodivergent Synthesis of Vinyl Halides
Christine M. Le, Perry J. C. Menzies, David A. Petrone and Mark Lautens Angew. Chem. Int. Ed. 2015, 54, 254-257. DOI: 10.1002/anie.201409248 .


326. Pd(0)-Catalyzed Carboiodination: Early Developments to Recent Advancements
David A. Petrone, Christine M. Le, Stephen G. Newman and Mark Lautens RSC 2015, New Trends in Cross-Coupling, 276-321. DOI: 10.1039/9781782620259-00276 .


2014

325. Diastereoselective Palladium-Catalyzed Arylcyanation/Heteroarylcyanation of Enantioenriched N-Allylcarboxamides
Hyung Yoon, David A. Petrone and Mark Lautens Org. Lett. 2014, 16(24), 6420-6423. DOI: 10.1021/ol503243a .


324. Metal-Ligand Binding Interactions in Rhodium/Palladium-Catalyzed Synthesis of Dihydroquinolines
Lei Zhang, Jane Panteleev, and Mark Lautens J. Org. Chem. 2014, 79(24), 12159-12176. DOI: 10.1021/jo502074s .


323. Rhodium-Catalyzed Arylative Cyclization for the Enantioselective Synthesis of (Trifluoromethyl)cyclobutanols
Thomas Johnson, Ken-Loon Choo and Mark Lautens Chem. Eur. J. 2014, 20(44), 14194-14197. DOI: 10.1002/chem.201404896 .


322. Sequential Rhodium/Palladium Catalysis: Enantioselective Formation of Dihydroquinolinones in the Presence of Achiral and Chiral Ligands
Lei Zhang, Zafar Qureshi, Lorenzo Sonaglia, and Mark Lautens Angew. Chem. Int. Ed. 2014, 53, 13850-13853. DOI: 10.1002/anie.201407400 .


321. Computational and 13C Investigations of the Diazadienes and Oxazadienes Formed via the Rearrangement of Methylenecyclopropyl Hydrazones and Oximes
Bo Chen, Mark E. Scott, Bruce A. Adams, David A. Hrovat, Weston Thatcher Borden, and Mark Lautens Org. Lett. 2014, 16, 3930-3933. DOI: 10.1021/ol501710m .


320. Additive Effects in the Palladium-Catalyzed Carboiodination of Chiral N-Allyl Carboxamides
David A Petrone, Hyung Yoon, Harald Weinstabl, and Mark Lautens Angew. Chem. Int. Ed. 2014, 53, 7908-7912. DOI: 10.1002/anie.201404007 .


319. Sulfur–silicon bond activation catalysed by Cl/Br ions: waste-free synthesis of unsymmetrical thioethers by replacing fluoride catalysis and fluorinated substrates in SNAr reactions
Xiaojuan Jia, Lei Yu, Jianping Liu, Qing Xu, Marcel Sickert, Lianhui Chena, and Mark Lautens Green Chem. 2014, 16, 3444-3449. DOI: 10.1039/C4GC00535J .


318. Application of the Palladium-Catalysed Norbornene-Assisted Catellani Reaction Towards the Total Synthesis of (+)-Linoxepin and Isolinoxepin
Zafar Qureshi, Harald Weinstabl, Marcel Suhartono, Hongqiang Liu, Pierre Thesmar, and Mark Lautens Eur. J. Org. Chem. 2014, , 4053-4069. DOI: 10.1002/ejoc.201402218 .


317. The Use of Silyl Ketene Acetals and Enol Ethers in the Catalytic Enantioselective Alkylative Ring Opening of Oxa/Aza Bicyclic Alkenes
Lei Zhang, Christine M. Le, and Mark Lautens Angew. Chem. Int. Ed. 2014, 53, 5951-5954. DOI: 10.1002/anie.201400218 .


316. Practical and scalable preparation of 2-methyleneglutaronitrile via an efficient and highly selective head-to-tail dimerization of acrylonitrile catalysed by low-loading tricyclohexylphosphine
Lei Yu, Jun Wang, Xu Zhang, Hongen Cao, Genlin Wang, Kehong Ding, Qing Xu, and Mark Lautens RSC Adv. 2014, 4, 19122-19126. DOI: 10.1039/C4RA02810D .


315. Intermolecular Domino Reaction of Two Aryl Iodides Involving Two C-H Functionalizations
Marcel Sickert, Harald Weinstabl, Brendan Peters, Xiao Hou, and Mark Lautens Angew. Chem. Int. Ed. 2014, 53, 5147-5151. DOI: 10.1002/anie.201400807 .


314. Organoselenium-Catalyzed Mild Dehydration of Aldoximes: An Unexpected Practical Method for Organonitrile Synthesis
Lei Yu, Hongyan Li, Xu Zhang, Jianqing Ye, Jianping Liu, Qing Xu, and Mark Lautens Org. Lett. 2014, 16, 1346-1349. DOI: 10.1021/ol500075h .


313. Multicomponent-Multicatalyst Reactions (MC)2R: Efficient Dibenzazepine Synthesis
Jennifer Tsoung, Jane Panteleev, Matthias Tesch, and Mark Lautens Org. Lett. 2014, 16, 110-113. DOI: 10.1021/ol4030925 .


2013

312. A Palladium-Catalyzed Domino Reaction as Key Step for the Synthesis of Functionalized Aromatic Amino Acids
Tina Stark, Marcel Suhartono, Michael W. Göbel, Mark Lautens Synlett 2013, 24, 2730-2734. DOI: 10.1055/s-0033-1339892 .


311. Harnessing Reversible Oxidative Addition: Application of Diiodinated Aromatic Compounds in the Carboiodination Process
David A. Petrone, Matthias Lischka, and Mark Lautens Angew. Chem. Int. Ed. 2013, 52, 10635-10638. DOI: 10.1002/anie.201304923 .


310. Palladium(II)-Catalyzed Enantioselective Synthesis of a-(Trifluoromethyl)arylmethylamines
Thomas Johnson and Mark Lautens Org. Lett. 2013, 15, 4043-4045. DOI: 10.1021/ol401862g .


309. Rh/Pd Catalysis with Chiral and Achiral Ligands: Domino Synthesis of Aza-Dihydrodibenzoxepines
Adam A. Friedman, Jane Panteleev, Jennifer Tsoung, Vaizanne Huynh, and Mark Lautens Angew. Chem. Int. Ed. 2013, 52, 9755-9758. DOI: 10.1002/anie.201303659 .


308. Gold Meets Rhodium: Tandem One-Pot Synthesis of ?Disubstituted Ketones via Meyer–Schuster Rearrangement and Asymmetric 1,4-Addition
Max M. Hansmann, A. Stephen K. Hashmi, and Mark Lautens Org. Lett. 2013, 15, 3226-3229. DOI: 10.1021/ol4011739 .


307. Metal-Ligand Binding Affinity vs Reactivity: Qualitative Studies in Rh(I)-Catalyzed Asymmetric Ring-Opening Reactions
Gavin Chit Tsui, Patrick Dougan, and Mark Lautens Org. Lett. 2013, 15, 2652-2655. DOI: 10.1021/ol4009393 .


306. Multicomponent Multicatalyst Reactions (MC)2R: One-Pot Synthesis of 3,4-Dihydroquinolinones
Lei Zhang, Lorenzo Sonaglia, Jason Stacey, and Mark Lautens Org. Lett. 2013, 15, 2128-2131. DOI: 10.1021/ol4006008 .


305. Total Synthesis of (+)-Linoxepin by Utilizing the Catellani Reaction
Harald Weinstabl, Marcel Suhartono, Zafar Qureshi, and Mark Lautens Angew. Chem. Int. Ed. 2013, 52, 5305-5308. DOI: 10.1002/anie.201302327 .


304. Synthesis of Heterocycles via Metal-Catalyzed Domino/One-Pot Reactions That Generate a C—N or C—O Bond
Juliane Keilitz, Hasnain A. Malik, Mark Lautens Top. Heterocycl. Chem. 2013, 32, 187-223. DOI: 10.1007/7081_2013_106 .

303. Enantioselective Rh-Catalyzed Domino Transformations of Alkynylcyclohexadienones with Organoboron Reagents
Juliane Keilitz , Stephen G. Newman , and Mark Lautens Org. Lett. 2013, 15, 1148-1151. DOI: 10.1021/ol400363f .


302. Expedient Synthesis of Chiral Oxazolidinone Scaffolds via Rhodium-Catalyzed Asymmetric Ring-Opening with Sodium Cyanate
Gavin Chit Tsui, Nina M. Ninnemann, Akihito Hosotani, and Mark Lautens Org. Lett. 2013, 15, 1064-1067. DOI: 10.1021/ol4000668 .


301. Domino C-H Functionalization Reactions of gem-Dibromoolefins: Synthesis of N-fused benzo[c]carbazoles
Richard Y. Huang, Patrick T. Franke, Norman Nicolaus, and Mark Lautens Tetrahedron 2013, 22, 4395-4402. DOI: 10.1016/j.tet.2013.01.001 .


2012

300. Rhodium-Catalyzed Enantioselective Nucleophilic Fluorination: Ring Opening of Oxabicyclic Alkenes
Jiangtao Zhu, Gavin C. Tsui, and Mark Lautens Angew. Chem. Int. Ed. 2012, 51, 12353-12356. DOI: 10.1002/anie.201207356 .


299. One-Pot Synthesis of Chiral Dihydrobenzofuran Framework via Rh/Pd Catalysis
Gavin C. Tsui, Jennifer Tsoung, Patrick Dougan, and Mark Lautens Org. Lett. 2012, 14, 5542-5545. DOI: 10.1021/ol302646a .


298. Functionalized Chromans and Isochromans via a Diastereoselective Pd(0)-Catalyzed Carboiodination
David A. Petrone, Hasnain A. Malik, Antonin Clemenceau, and Mark Lautens Org. Lett. 2012, 14, 4806-4809. DOI: 10.1021/ol302111y .


297. Development of an Intramolecular Aryne Ene Reaction and Application to the Formal Synthesis of (?-Crinine
David A. Candito, Dennis Dobrovolsky, and Mark Lautens J. Am. Chem. Soc. 2012, 134, 15572-15580. DOI: 10.1021/ja306881u .


296. A Conjunctive Carboiodination: Indenes by a Double Carbopalladation-Reductive Elimination Domino Process
Xiaodong Jia, David A. Petrone, and Mark Lautens Angew. Chem. Int. Ed. 2012, 51, 9870-9872. DOI: 10.1002/anie.201204716 .


295. Expeditious Synthesis of Tetrasubstituted Helical Alkenes by a Cascade of Palladium-Catalyzed C-H Activations
Hongqiang Liu, Mohamed El-Salfiti, and Mark Lautens Angew. Chem. Int. Ed. 2012, 51, 9846-9850. DOI: 10.1002/anie.201204226 .


294. Modular and Stereoselective Synthesis of Tetrasubstituted Helical Alkenes via a Palladium-Catalyzed Domino Reaction
Hongqiang Liu, Mohamed El-Salfiti, David I. Chai, Jérémy Auffret and Mark Lautens Org. Lett. 2012, 14, 3648-3651. DOI: 10.1021/ol301495q .


293. Rhodium(I)-Catalyzed Domino Asymmetric Ring Opening/Enantioselective Isomerization of Oxabicyclic Alkenes with Water
Gavin C. Tsui and Mark Lautens Angew. Chem. Int. Ed. 2012, 51, 5400-5404. DOI: 10.1002/anie.201200390 .


292. Use of (Z)-?(2-Fluorobenzenesulfonyl)vinylamines as Novel Synthons in the Synthesis of 1,4-Benzothiazine Derivatives
Gavin Tsui, Yuttapong Singjunla, and Mark Lautens Synthesis 2012, 44, 1359-1364. DOI: 10.1055/s-0031-1289741 .


291. Theoretical Study of Pd(0)-Catalyzed Carbohalogenation of Alkenes: Mechanism and Origins of Reactivities and Selectivities in Alkyl Halide Reductive Elimination from Pd(II) Species
Yu Lan, Peng Liu, Stephen G. Newman, Mark Lautens, and K. N. Houk Chem. Sci. 2012, 3, 1987-1995. DOI: 10.1039/C2SC20103H .


290. Synthesis of 1,2,3-triazole-fused heterocycles via Pd-catalyzed cyclization of 5-iodotriazoles
Jacqueline M. Schulman, Adam A. Friedman, Jane Panteleev, and Mark Lautens Chem. Commun. 2012, 48, 55-57. DOI: 10.1039/C1CC16110E .


2011

289. Synthesis of Unsymmetrical Polysubstituted Pyridines from ?Sulfonylvinylamines via 1-Aza-Allyl Anion Intermediates
Chan Lau, Gavin Chit Tsui, and Mark Lautens Synthesis 2011, 2011, 3908-3914. DOI: 10.1055/s-0031-1289578 .


288. Diastereoselective Friedel–Crafts Alkylation of Hydronaphthalenes
Jennifer Tsoung, Katja Krämer, Adam Zajdlik, Clemence Liébert, and Mark Lautens J. Org. Chem. 2011, 76, 9031-9045. DOI: 10.1021/jo201781x .


287. Addition of Arylboronic Acids to Arylpropargyl Alcohols en Route to Indenes and Quinolines
Jane Panteleev, Richard Y. Huang, Erica K. J. Lui, and Mark Lautens Org. Lett. 2011, 13, 5314-5317. DOI: 10.1021/ol202176g .


286. Palladium-Catalyzed Carbohalogenation: Bromide to Iodide Exchange and Domino Processes
Stephen G. Newman, Jennifer K. Howell, Norman Nicolaus, and Mark Lautens J. Am. Chem. Soc. 2011, 133, 14916-14919. DOI: 10.1021/ja206099t .


285. Domino Rhodium-Catalyzed Alkyne Arylation/Palladium-Catalyzed N Arylation: A Mechanistic Investigation
Jane Panteleev, Lei Zhang, and Mark Lautens Angew. Chem. Int. Ed. 2011, 50, 9089-9092. DOI: 10.1002/anie.201103692 .


284. Intramolecular Aryne–Ene Reaction: Synthetic and Mechanistic Studies
David A. Candito, Jane Panteleev, and Mark Lautens J. Am. Chem. Soc. 2011, 133, 14200-14203. DOI: 10.1021/ja205405n .


283. Stereoselective Nickel-Catalyzed [2+2+2] Cycloaddition of Enynes and Arynes
David A. Candito and Mark Lautens Synlett 2011, 2011, 1987-1992. DOI: 10.1055/s-0030-1261171 .


282. Modular Synthesis of Naphthothiophenes by Pd-Catalyzed Tandem Direct Arylation/Suzuki Coupling
Norman Nicolaus, Patrick T. Franke, and Mark Lautens Org. Lett. 2011, 13, 4236-4239. DOI: 10.1021/ol201585a .


281. Rhodium-Catalyzed Domino Enantioselective Synthesis of Bicyclo[2.2.2]lactones
Alistair Boyer, Mark Lautens Angew. Chem. Int. Ed. 2011, 50, 7346-7349. DOI: 10.1002/anie.201101773 .


280. Mechanistic Studies of Pd-Catalyzed Regioselective Aryl CH Bond Functionalization with Strained Alkenes: Origin of Regioselectivity
David I. Chai, Praew Thansandote and Mark Lautens Chem. Eur. J. 2011, 17, 8175-8188. DOI: 10.1002/chem.201100210 .


279. Diastereoselective Intramolecular Friedel–Crafts Alkylation of Tetralins
Clémence Liébert, Marion K. Brinks, Andrew G. Capacci, Matthew J. Fleming and Mark Lautens Org. Lett. 2011, 13, 3000-3003. DOI: 10.1021/ol2008236 .


278. Formal Synthesis of Nitidine and NK109 via Palladium-Catalyzed Domino Direct Arylation/N-Arylation of Aryl Triflates
Mathieu Blanchot, David A. Candito, Florent Larnaud and Mark Lautens Org. Lett. 2011, 13, 1486-1489. DOI: 10.1021/ol200174g .


277. Rh(I)-Catalyzed Ring-Opening of Hetaryne-Furan Diels-Alder Adducts: Rapid Access to Stereochemically Defined Heterocyclic Scaffolds
Trung D. Nguyen, Robert Webster and Mark Lautens Org. Lett. 2011, 13, 1370-1373. DOI: 10.1021/ol200057j .


276. Palladium-Catalyzed Carboiodination of Alkenes: Carbon-Carbon Bond Formation with Retention of Reactive Functionality
Stephen G. Newman and Mark Lautens J. Am. Chem. Soc. 2011, 133, 1778-1780. DOI: 10.1021/ja110377q .


275. Enantioselective Palladium-Catalyzed Carbozincation of Cyclopropenes
Katja Krämer, Paul Leong and Mark Lautens Org. Lett. 2011, 13, 819-821. DOI: 10.1021/ol1029904.


274. The Use of Bromotrichloromethane in Chlorination Reactions
Stephen G. Newman, Christopher S. Bryan, Didier Perez, Mark Lautens Synthesis 2011, 2011, 342-346. DOI: 10.1055/s-0030-1258368 .


273. Rhodium(I)-Catalyzed Addition of Arylboronic Acids to (Benzyl-/Arylsulfonyl)acetonitriles: Efficient Synthesis of (Z)-β-Sulfonylvinylamines and β-Keto Sulfones
Gavin C. Tsui, Quentin Glenadel, Chan Lau, and Mark Lautens Org. Lett. 2011, 13, 208-211. DOI: 10.1021/ol102598p .


272. Synthesis of 2-Oxazolones and α-Aminoketones via Palladium-Catalyzed Reaction of β,β-Dibromoenamides
David I. Chai, Laura Hoffmeister, and Mark Lautens Org. Lett. 2011, 13, 106-109. DOI: 10.1021/ol102634c.


2010

271. Synthesis in the Key of Catellani: Norbornene-Mediated ortho C-H Functionalization
Martins, A.; Mariampillai, B.; Lautens, M. Topics in Current Chemistry 2010, 292, 1-33. DOI: 10.1007/978-3-642-12356-6 .

270. Practical Asymmetric Synthesis of Bioactive Aminotetralins from a Racemic Precursor Using a Regiodivergent Resolution
Robert Webster, Alistair Boyer, Matthew J. Fleming, and Mark Lautens Org. Lett. 2010, 12, 5418-5421. DOI: 10.1021/ol1022239 .


269. Palladium-Catalyzed Reductive ortho-Arylation: Evidence for the Decomposition of 1,2-Dimethoxyethane and Subsequent Arylpalladium(II) Reduction
Andrew Martins, David A. Candito, and Mark Lautens Org. Lett. 2010, 12, 5186-5188. DOI: 10.1021/ol1019037 .


268. C-H Bond Functionalization in the Synthesis of Fused 1,2,3-Triazoles
Jane Panteleev, Karolin Geyer, Angelica Aguilar-Aguilar, Letian Wang, and Mark Lautens Org. Lett. 2010, 12, 5092-5095. DOI: 10.1021/ol102342y .


267. Linear-Selective Rhodium(I)-Catalyzed Addition of Arylboronic Acids to Allyl Sulfones
Gavin C. Tsui and Mark Lautens Angew. Chem. Int. Ed. 2010, 47, 8938-8941. DOI: 10.1002/anie.201004345 .


266. The Role of Reversible Oxidative Addition in Selective Palladium(0)-Catalyzed Intramolecular Cross-Couplings of Polyhalogenated Substrates: Synthesis of Brominated Indoles
Stephen G. Newman and Mark Lautens J. Am. Chem. Soc. 2010, 132, 11416-11417. DOI: 10.1021/ja1052335.


265. Exploiting the Chemistry of Strained Rings: Synthesis of Indoles via Domino Reaction of Aryl Iodides with 2H-Azirines
David A. Candito and Mark Lautens Org. Lett. 2010, 12, 3312-3315. DOI: 10.1021/ol100975b.


264. A Rhodium IBiox[(-)-menthyl] Complex as a Highly Selective Catalyst for the Asymmetric Hydroarylation of Azabicyles: An Alternative Route to Epibatidine
Jason Bexrud and Mark Lautens Org. Lett. 2010, 12, 3160-3163. DOI: 10.1021/ol101067d.


263. Domino rhodium(I)-catalysed reactions for the efficient synthesis of substituted benzofurans and indoles
Alistair Boyer, Naohiro Isono, Sebastian Lackner, Mark Lautens Tetrahedron 2010, 66, 6468-6482. DOI: 10.1016/j.tet.2010.05.106.


262. A Tandem Catalytic Approach to Methyleneindenes: Mechanistic Insights into gem-Dibromoolefin Reactivity
Christopher S. Bryan and Mark Lautens Org. Lett. 2010, 12, 2754-2757. DOI: 10.1021/ol100844v.


261. Ligand-Controlled Selectivity in the Desymmetrization of meso Cyclopenten-1,4-diols via Rhodium(I)-Catalyzed Addition of Arylboronic Acids
Frederic Menard, David Perez, Daniela Sustac Roman, Timothy M. Chapman and Mark Lautens J. Org. Chem. 2010, 75, 4056-4068. DOI: 10.1021/jo100391e.


260. Regioselective Rhodium(I)-Catalyzed Hydroarylation of Protected Allylic Amines with Arylboronic Acids
Gavin Chit Tsui, Frederic Menard and Mark Lautens Org. Lett. 2010, 12, 2456-2459. DOI: 10.1021/ol100974f.


259. Palladium-Catalyzed Domino C-C/C-N Coupling Using a Norbornene Template: Synthesis of Substituted Benzomorpholines, Phenoxazines, and Dihydrodibenzoxazepines
Praew Thansandote, Eugene Chong, Kai-Oliver Feldmann and Mark Lautens J. Org. Chem. 2010, 75, 3495-3498. DOI: 10.1021/jo100408p.


258. Diastereoselective Benzylic Arylation of Tetralins
Davoust, M; Kitching, JA; Fleming, MJ; Lautens, M Chem. Eur. J. 2010, 16, 50-54. DOI: 10.1002/chem.200902694.


2009

257. Conformational Effects in Diastereoselective Aryne Diels-Alder Reactions: Synthesis of Benzo-Fused [2.2.1] Heterobicycles
Webster, R; Lautens, M Org. Lett. 2009, 11, 4688-4691. DOI: 10.1021/ol9019869.


256. New hydronaphthalene compounds useful for preparing active pharmaceutical ingredients e.g. (6S)-5,6,7,8-tetrahydro-6-(propyl(2-(2-thienyl)ethyl)amino)-1-naphthalenol
Fleming, MJ; Lautens, M; Spielvogel, D; Thommen, M 2009, EP2098511-A1; WO2009109648-A1-.


255. Efficient Synthesis of Benzothiophenes by an Unusual Palladium-Catalyzed Vinylic C-S Coupling
Bryan, CS; Braunger, JA; Lautens, M Angew. Chem. Int. Ed. 2009, 48, 7064-7068. DOI: 10.1002/anie.200902843.


254. Intramolecular cross-coupling of gem-dibromoolefins: a mild approach to 2-bromo benzofused heterocycles
Newman, SG; Aureggi, V; Bryan, CS; Lautens, M Chem. Commun. 2009, 5236-5238. DOI: 10.1039/b912093a.


253. Palladium-Catalyzed Domino Direct Arylation/N-Arylation: Convenient Synthesis of Phenanthridines
Candito, DA; Lautens, M Angew. Chem. Int. Ed. 2009, 48, 6713-6716. DOI: 10.1002/anie.200902400.


252. Construction of Nitrogen-Containing Heterocycles by C-H Bond Functionalization
Thansandote, P; Lautens, M Chem. Eur. J. 2009, 15, 5874-5883. DOI: 10.1002/chem.200900281.

251. A Convenient Synthesis of Indolo- and Pyrrolobenzazepines via a Threefold Norbornene-Mediated Domino Reaction
Aureggi, V; Davoust, M; Gericke, KM; Lautens, M Synlett 2009, 1004-1008. DOI: 10.1055/s-0028-1088195.

250. Tandem Pd-Catalyzed Double C-C Bond Formation: Effect of Water
Chai, DI; Lautens, M J. Org. Chem. 2009, 74, 3054-3061. DOI: 10.1021/jo900053b.

249. Secondary Alkyl Halides in Transition-Metal-Catalyzed Cross-Coupling Reactions
Rudolph, A; Lautens, M Angew. Chem. Int. Ed. 2009, 48, 2656-2670. DOI: 10.1002/anie.200803611.

248. Synthesis of Homoallylic Alcohols via Lewis Acid Assisted Enantioselective Desymmetrization
Yu, B; Menard, F; Isono, N; Lautens, M Synthesis 2009, 853-859. DOI: 10.1055/s-0028-1083368.

247. Rhodium-Catalyzed Vinylcyclopropanation/Cyclopentenation of Strained Alkenes via a Sequential Carborhodation Process
Tseng, NW; Lautens, M J. Org. Chem. 2009, 74, 2521-2526. DOI: 10.1021/jo900039g.

246. Rhodium(I)-Catalyzed Cyclization Reaction of o-Alkynyl Phenols and Anilines. Domino Approach to 2,3-Disubstituted Benzofurans and Indoles
Isono, N; Lautens, M Org. Lett. 2009, 11, 1329-1331. DOI: 10.1021/ol9001174.

245. Exploiting the Divergent Reactivity of Aryl-Palladium Intermediates for the Rapid Assembly of Fluorene and Phenanthrene Derivatives
Zhao, YB; Mariampillai, B; Candito, DA; Laleu, B; Li, MZ; Lautens, M Angew. Chem. Int. Ed. 2009, 48, 1849-1852. DOI: 10.1002/anie.200805780.

244. Application of a Rhodium-Catalyzed Addition/Cyclization Sequence toward the Synthesis of Polycyclic Heteroaromatics
Tseng, NW; Lautens, M J. Org. Chem. 2009, 74, 1809-1811. DOI: 10.1021/jo802622d.

243. The Norbornene Shuttle: Multicomponent Domino Synthesis of Tetrasubstituted Helical Alkenes through Multiple C-H Functionalization
Gericke, KM; Chai, DI; Bieler, N; Lautens, M Angew. Chem. Int. Ed. 2009, 48, 1447-1451. DOI: 10.1002/anie.200805512.

242. Palladium-Catalyzed Annulation of Haloanilines and Halobenzamides Using Norbornadiene as an Acetylene Synthon: A Route to Functionalized Indolines, Isoquinolinones, and Indoles
Thansandote, P; Hulcoop, DG; Langer, M; Lautens, M J. Org. Chem. 2009, 74, 1673-1678. DOI: 10.1021/jo802604g.

241. A Rapid Approach to the Synthesis of Highly Functionalized Tetrahydroisoquinolines
Thansandote, P; Gouliaras, C; Turcotte-Savard, MO; Lautens, M J. Org. Chem. 2009, 74, 1791-1793. DOI: 10.1021/jo8025725.

240. Discovery of mu-opioid selective ligands derived from 1-aminotetralin scaffolds made via metal-catalyzed ring-opening reactions
Dockendorff, C; Jin, SJ; Olsen, M; Lautens, M; Coupal, M; Hodzic, L; Spear, N; Payza, K; Walpole, C; Tomaszewski, MJ Bioorg. Med. Chem. Lett. 2009, 19, 1228-1232. DOI: 10.1016/j.bmcl.2008.12.095.

239. Application of Secondary Alkyl Halides to a Domino Aryl Alkylation Reaction for the Synthesis of Aromatic Heterocycles
Rudolph, A; Rackelmann, N; Turcotte-Savard, MO; Lautens, M J. Org. Chem. 2009, 74, 289-297. DOI: 10.1021/jo802180h.

238. Bifunctional Reactivity of Cu-I: Sequential Ring Opening/N-Arylation
Martins, A; Lemouzy, S; Lautens, M Org. Lett. 2009, 11, 181-183. DOI: 10.1021/ol802357e.

237. Reagent-Controlled Regiodivergent Resolution of Unsymmetrical Oxabicyclic Alkenes Using a Cationic Rhodium Catalyst
Webster, R; Boing, C; Lautens, M J. Am. Chem. Soc. 2009, 131, 444-445. DOI: 10.1021/ja807942m.

2008

236. Ligand Control in Enantioselective Desymmetrization of Bicyclic Hydrazines: Rhodium(I)-Catalyzed Ring-Opening versus Hydroarylation
Panteleev, J; Menard, F; Lautens, M Adv. Synth. Catal. 2008, 350, 2893-2902. DOI: 10.1002/adsc.200800587.

235. Preparation of 2-substituted indole compound useful as precursor in synthesis of e.g. indole alkaloid, by reacting ortho-gem-dibromovinylaniline compound with alkene Heck acceptor in the presence of base and palladium metal pre-catalyst
LAUTENS M; FAYOL A; NAGAMOCHI M; FANG Y 2008, WO2007134421-A1-.

234. Aromatic ortho-Benzylation Reveals an Unexpected Reductant
Martins, A; Lautens, M Org. Lett. 2008, 10, 5095-5097. DOI: 10.1021/ol802185x.

233. Preparing substituted azaindole compound, to e.g. treat scleroderma, comprises reacting ortho-gem-dihalovinylaminopyridine compound with organoboron reagent e.g. boronic acid in the presence of base, palladium metal pre-catalyst and ligand
LAUTENS M; YUEN J; FANG Y 2008, WO2008022467-A1-.

232. A Palladium-Catalyzed Approach to Polycyclic Sulfur Heterocycles
Martins, A; Lautens, M J. Org. Chem. 2008, 73, 8705-8710. DOI: 10.1021/jo8020105.

231. Synthesis of Annulated 2H-Indazoles and 1,2,3-and 1,2,4-Triazoles via a One-Pot Palladium-Catalyzed Alkylation/Direct Arylation Reaction
Laleu, B; Lautens, M J. Org. Chem. 2008, 73, 9164-9167. DOI: 10.1021/jo8017236.

230. Synthesis of Highly Functionalized Pyrrolidines via a Selective Iodide-Mediated Ring Expansion of Methylenecyclopropyl Amides
Scott, ME; Lautens, M J. Org. Chem. 2008, 73, 8154-8162. DOI: 10.1021/jo802049u.

229. A simple, cost-effective method for the regioselective deuteration of anilines
Martins, A; Lautens, M Org. Lett. 2008, 10, 4351-4353. DOI: 10.1021/ol801763j.

228. Silver-Promoted Domino Pd-Catalyzed Amination/Direct Arylation: Access to Polycyclic Heteroaromatics
Bryan, CS; Lautens, M Org. Lett. 2008, 10, 4633-4636. DOI: 10.1021/ol801932z.

227. Rhodium-catalyzed ring-opening reactions of N-Boc-azabenzonorbornadiene with chiral amine nucleophiles derived from amino acids
Cho, YH; Tseng, NW; Senboku, H; Lautens, M Synthesis 2008, 2467-2475. DOI: 10.1055/s-2008-1078596.

226. The versatile role of norbornene in C-H functionalization processes: concise synthesis of tetracyclic fused pyrroles via a threefold domino reaction
Gericke, KM; Chai, DI; Lautens, M Tetrahedron 2008, 64, 6002-6014. DOI: 10.1016/j.tet.2008.01.146.

225. Concise enantioselective total syntheses of (+)-homochelidonine, (+)-chelamidine, (+)-chelidonine, (+)-chelamine and (+)-norchelidonine by a Pd-II-catalyzed ring-opening strategy
Fleming, MJ; McManus, HA; Rudolph, A; Chan, WH; Ruiz, J; Dockendorff, C; Lautens, M Chem. Eur. J. 2008, 14, 2112-2124. DOI: 10.1002/chem.200701775.

224. Horner-Wadsworth-Emmons modification for Ramirez gem-dibromoolefination of aldehydes and ketones using P(Oi-Pr)(3)
Fang, YQ; Lifchits, O; Lautens, M Synlett 2008, 413-417. DOI: 10.1055/s-2008-1032045.

223. A palladium-catalyzed alkylation/direct arylation synthesis of nitrogen-containing heterocycles
Blaszykowski, C; Aktoudianakis, E; Adberico, D; Bressy, C; Hulcoop, DG; Jafarpour, F; Joushaghani, A; Laleu, B; Lautens, M J. Org. Chem. 2008, 73, 1888-1897. DOI: 10.1021/jo702052b.

222. Chemodivergence in enantioselective desymmetrization of diazabicycles: Ring-opening versus reductive arylation
Menard, F; Lautens, M Angew. Chem. Int. Ed. 2008, 47, 2085-2088. DOI: 10.1002/anie.200704708.

221. Enzymatic resolution of chlorohydrins for the synthesis of enantiomerically enriched 2-vinyloxiranes
McCubbin, JA; Maddess, ML; Lautens, M Synlett 2008, 289-293. DOI: 10.1055/s-2007-1000845.

220. A highly selective tandem cross-coupling of gem-dihaloolefins for a modular, efficient synthesis of highly functionalized indoles
Fang, YQ; Lautens, M J. Org. Chem. 2008, 73, 538-549. DOI: 10.1021/jo701987r.

2007

219. Use of a sterically demanding Lewis acid to direct ring expansion of monoactivated methylenecyclopropanes
Taillier, C; Bethuel, Y; Lautens, M Tetrahedron 2007, 63, 8469-8477. DOI: 10.1016/j.tet.2007.05.081.

218. Rh(I)-catalyzed carbonylative ring opening of diazabicycles with acyl anion equivalents
Menard, F; Weise, CF; Lautens, M Org. Lett. 2007, 9, 5365-5367. DOI: 10.1021/ol7022054.

217. A convergent synthesis of polysubstituted aromatic nitriles via palladium-catalyzed C-H functionalization
Mariampillai, B; Alliot, J; Li, M; Lautens, M J. Am. Chem. Soc. 2007, 129, 15372-15379. DOI: 10.1021/ja075599i.

216. Synthesis of benzannulated N-heterocycles by a palladium-catalyzed C-C/C-N coupling of bromoalkylamines
Thansandote, P; Raemy, M; Rudolph, A; Lautens, M Org. Lett. 2007, 9, 5255-5258. DOI: 10.1021/ol702472u.

215. Stereochemical and mechanistic investigations of a palladium-catalyzed annulation of secondary alkyl iodides
Rudolph, A; Rackelmann, N; Lautens, M Angew. Chem. Int. Ed. 2007, 46, 1485-1488. DOI: 10.1002/anie.200603888.

214. Enantioselective total synthesis of (+)-homochelidonine by a Pd-II-catalyzed asymmetric ring-opening reaction of a meso-azabicyclic alkene with an aryl boronic acid
McManus, HA; Fleming, MJ; Lautens, M Angew. Chem. Int. Ed. 2007, 46, 433-436. DOI: 10.1002/anie.200603945.

213. A general and practical method of alkynyl indole and benzofuran synthesis via tandem Cu- and Pd-catalyzed cross-couplings
Nagamochi, M; Fang, YQ; Lautens, M Org. Lett. 2007, 9, 2955-2958. DOI: 10.1021/ol071370w.

212. A general modular method of azaindole and thienopyrrole synthesis via Pd-catalyzed tandem couplings of gem-dichloroolefins
Fang, YQ; Yuen, J; Lautens, M J. Org. Chem. 2007, 72, 5152-5160. DOI: 10.1021/jo070460b.

211. Palladium-catalyzed annulation of aryl heterocycles with strained alkenes
Hulcoop, DG; Lautens, M Org. Lett. 2007, 9, 1761-1764. DOI: 10.1021/ol070475w.

210. Convenient access to functionalized vinylcyclopentenols from alkynyloxiranes
Wang, LT; Maddess, ML; Lautens, M J. Org. Chem. 2007, 72, 1822-1825. DOI: 10.1021/jo062107w.

209. Efficient syntheses of KDR kinase inhibitors using a Pd-catalyzed tandem C-N/Suzuki coupling as the key step
Fang, YQ; Karisch, R; Lautens, M J. Org. Chem. 2007, 72, 1341-1346. DOI: 10.1021/jo062228w.

208. Enantioselective catalytic ring expansion of methylenecyclopropane carboxamides promoted by a chiral magnesium Lewis acid
Taillier, C; Lautens, M Org. Lett. 2007, 9, 591-593. DOI: 10.1021/ol0628614.

207. A highly efficient and selective route to isomeric cyclic diazadienes
Scott, ME; Bethuel, Y; Lautens, M J. Am. Chem. Soc. 2007, 129, 1482-1483. DOI: 10.1021/ja067304r.

206. Synthesis of tricyclic heterocycles via a tandem aryl alkylation/heck coupling sequence
Alberico, D; Rudolph, A; Lautens, M J. Org. Chem. 2007, 72, 775-781. DOI: 10.1021/jo0617868.

205. Aryl-aryl bond formation by transition-metal-catalyzed direct arylation
Alberico, D; Scott, ME; Lautens, M Chem. Rev. 2007, 107, 174-238. DOI: 10.1021/cr0509760.

2006

204. Preparation of 2-substituted indole compound, useful for the synthesis of e.g. fluvastatin, comprises reacting ortho-gem-dihalovinylaniline compound with organoboron reagent in the presence of base, palladium metal pre-catalyst and ligand
LAUTENS M; FANG Y 2006, WO2006047888-A1; EP1817283-A1; US2008039625-A1-.

203. Synthesis of beta,gamma-unsaturated lactams via a magnesium iodide promoted ring expansion of secondary - Methylenecyclopropyl Amides
Scott, ME; Schwarz, CA; Lautens, M Org. Lett. 2006, 8, 5521-5524. DOI: 10.1021/ol0621957.

202. Synthesis of polycyclic benzonitriles via a one-pot aryl alkylation/cyanation reaction
Mariampillai, B; Alberico, D; Bidau, V; Lautens, M J. Am. Chem. Soc. 2006, 128, 14436-14437. DOI: 10.1021/ja064742p.

201. Palladium-catalyzed alkylation-alkenylation reactions: Rapid access to tricyclic mescaline analogues
Alberico, D; Lautens, M Synlett 2006, 2969-2972. DOI: 10.1055/s-2006-941583.

200. Synthesis of polycyclic heterocycles via a one-pot ortho alkylation/direct heteroarylation sequence
Martins, A; Alberico, D; Lautens, M Org. Lett. 2006, 8, 4827-4829. DOI: 10.1021/ol061859+.

199. Rhodium-catalyzed asymmetric allylic substitution with boronic acid nucleophiles
Menard, F; Chapman, TM; Dockendorff, C; Lautens, M Org. Lett. 2006, 8, 4569-4572. DOI: 10.1021/ol061777l.

198. Synthesis of 2-vinylic indoles and derivatives via a Pd-catalyzed tandem coupling reaction
Fayol, A; Fang, YQ; Lautens, M Org. Lett. 2006, 8, 4203-4206. DOI: 10.1021/ol061374l.

197. Selectively substituted thiophenes and indoles by a tandem palladium-catalyzed multicomponent reaction
Mitsudo, K; Thansandote, P; Wilhelm, T; Mariampillai, B; Lautens, M Org. Lett. 2006, 8, 3939-3942. DOI: 10.1021/ol061373t.

196. Synthesis of 1,2-dihydropyridines using vinyloxiranes as masked dienolates in imino-aldol reactions
Brunner, B; Stogaitis, N; Lautens, M Org. Lett. 2006, 8, 3473-3476. DOI: 10.1021/ol061086p.

195. Direct, one-step synthesis of condensed heterocycles: A palladium-catalyzed coupling approach
Jafarpour, F; Lautens, M Org. Lett. 2006, 8, 3601-3604. DOI: 10.1021/ol061404k.

194. Total synthesis of cryptophycin analogues via a scaffold approach
McCubbin, JA; Maddess, ML; Lautens, M Org. Lett. 2006, 8, 2993-2996. DOI: 10.1021/ol0609356.

193. Synthesis of substituted benzoxacycles via a domino ortho-alkylation/Heck coupling sequence
Martins, A; Marquardt, U; Kasravi, N; Alberico, D; Lautens, M J. Org. Chem. 2006, 71, 4937-4942. DOI: 10.1021/jo0605521.

192. Rhodium-catalyzed ring-opening reactions of N-boc-azabenzonorbornadienes with amine nucleophiles
Cho, YH; Zunic, V; Senboku, H; Olsen, M; Lautens, M J. Am. Chem. Soc. 2006, 128, 6837-6846. DOI: 10.1021/ja0577701.

191. Preparation of annulated nitrogen-containing heterocycles via a one-pot palladium-catalyzed alkylation/direct arylation sequence
Blaszykowski, C; Aktoudianakis, E; Bressy, C; Alberico, D; Lautens, M Org. Lett. 2006, 8, 2043-2045. DOI: 10.1021/ol060447y.

190. 2,4-Dimethyl-6-phenyl-8-oxabicyclo[3.2.1]-octan-3-one
Dockendorff, C; Lautens, M; Lough, AJ Acta Cryst. 2006, E62, O1601-O1603. DOI: 10.1107/S1600536806009779.

189. Rhodium-catalyzed tandem vinylcyclopropanation of strained alkenes
Tseng, NW; Mancuso, J; Lautens, M J. Am. Chem. Soc. 2006, 128, 5338-5339. DOI: 10.1021/ja060877j.

188. 2-(1-phenylsulfonyl-1H-indol-3-yl)-1,2-dihydronaphthalen-1-ol
Dockendorff, C; Lautens, M; Lough, AJ Acta Cryst. 2006, E62, O1030-O1032. DOI: 10.1107/S1600536806004776.

187. Diastereoselective palladium-catalyzed formate reduction of allylic carbonates en route to polypropionate systems
Chau, A; Paquin, JF; Lautens, M J. Org. Chem. 2006, 71, 1924-1933. DOI: 10.1021/jo052267s.

186. 2-Methoxy-N-[2-(3-thienyl)-1,2,3,4-tetra-hydro-1-naphthyl]acetamide
Dockendorff, C; Lautens, M; Lough, AJ Acta Cryst. 2006, E62, O639-O641. DOI: 10.1107/S1600536806001036.

185. Palladium-catalyzed ring-forming reactions: Methods and applications
Lautens, M; Alberico, D; Bressy, C; Fang, YQ; Mariampillai, B; Wilhelm, T PURE AND APPLIED CHEMISTRY 2006, 78, 351-361. DOI: 10.1351/pac200678020351.

184. Cul-catalyzed tandem intramolecular amidation using gem-dibromovinyl systems
Yuen, J; Fang, YQ; Lautens, M Org. Lett. 2006, 8, 653-656. DOI: 10.1021/ol052840u.

183. Enantioselective synthesis of chiral 1,2-diamines by the catalytic ring opening of azabenzonorbornadienes: application in the preparation of new chiral ligands
Cho, YH; Fayol, A; Lautens, M Tetrahedron-ASYMMETRY 2006, 17, 416-427. DOI: 10.1016/j.tetasy.2005.12.024.

182. tert-Butyl (2-phenyl-1,2-dihydro-1-naphthyl)carbamate
Dockendorff, C; Lautens, M; Lough, AJ Acta Cryst. 2006, E62, O107-O108. DOI: 10.1107/S1600536805039747.

2005

181. Synthesis of dihydronaphthalenes via Aryne Diels-Alder reactions: Scope and diastereoselectivity
Dockendorff, C; Sahli, S; Olsen, M; Milhau, L; Lautens, M J. Am. Chem. Soc. 2005, 127, 15028-15029. DOI: 10.1021/ja055498p.

180. Intermolecular Heck-type coupling of aryl iodides and allylic acetates
Mariampillai, B; Herse, C; Lautens, M Org. Lett. 2005, 7, 4745-4747. DOI: 10.1021/ol051947e.

179. A route to annulated indoles via a palladium-catalyzed tandem alkylation/direct arylation reaction
Bressy, C; Alberico, D; Lautens, M J. Am. Chem. Soc. 2005, 127, 13148-13149. DOI: 10.1021/ja054472v.

178. Palladium-catalyzed alkylation-hydride reduction sequence: Synthesis of meta-substituted arenes
Wilhelm, T; Lautens, M Org. Lett. 2005, 7, 4053-4056. DOI: 10.1021/ol051628n .

177. Pd-catalyzed tandem C-N/C-C coupling of gem-dihalovinyl systems: A modular synthesis of 2-substituted indoles
Fang, YQ; Lautens, M Org. Lett. 2005, 7, 3549-3552. DOI: 10.1021/ol051286l.

176. Preparation of homoallylic homopropargylic alcohols from 2-vinyloxiranes
Maddess, ML; Lautens, M Org. Lett. 2005, 7, 3557-3560. DOI: 10.1021/ol051326l.

175. Total synthesis of (-)-(alpha)-kainic acid via a diastereoselective methylenecyclopropane ring expansion
Scott, ME; Lautens, M Org. Lett. 2005, 7, 3045-3047. DOI: 10.1021/ol051003p.

174. Palladium-catalyzed sequential alkylation-alkenylation reactions: application towards the synthesis of polyfunctionalized fused aromatic rings
Alberico, D; Paquin, JF; Lautens, M Tetrahedron 2005, 61, 6283-6297. DOI: 10.1016/j.tet.2005.03.128.

173. Palladium-catalyzed intramolecular coupling between aryl iodides and allyl moieties via thermal and microwave-assisted conditions
Lautens, M; Tayama, E; Herse, C J. Am. Chem. Soc. 2005, 127, 72-73. DOI: 10.1021/ja043898r.

2004

172. A highly diastereoselective MgI2-mediated ring expansion of methylenecyclopropanes
Scott, ME; Han, W; Lautens, M Org. Lett. 2004, 6, 3309-3312. DOI: 10.1021/ol048769u .

171. Carbon-Carbon Bond Formation Using Arylboron Reagents with Rh(I) Catalysts
Mancuso, J.; Yoshida, M.; Lautens, M. Catalysis for Fine Chemical Synthesis 2004, 3, 147-153.

170. Rhodium-catalyzed Heck-type coupling of boronic acids with activated alkenes in an aqueous emulsion
Lautens, M; Mancuso, J; Grover, H Synthesis 2004, 2006-2014. DOI: 10.1055/s-2004-829161.

169. Rhodium-catalyzed tandem cyclization: Formation of 1H-indenes and 1-alkylideneindans from arylboronate esters in aqueous media
Lautens, M; Marquardt, T J. Org. Chem. 2004, 69, 4607-4614. DOI: 10.1021/jo049722p.

168. Activation and stabilization of aldimines by an ortho-trifluoromethyl substituent in direct vinylogous Mannich-type reactions
Lautens, M; Tayama, E; Nguyen, D Tetrahedron Lett. 2004, 45, 5131-5133. DOI: 10.1016/j.tetlet.2004.04.165.

167. Preparation and utility of cyclic enol carbonates
Maddess, ML; Lautens, M Synthesis 2004, 1399-1408. DOI: 10.1055/s-2004-822401.

166. Chemoselective cross metathesis of bishomoallylic alcohols: Rapid access to fragment A of the cryptophycins
Lautens, M; Maddess, ML Org. Lett. 2004, 6, 1883-1886. DOI: 10.1021/ol0498831.

165. Allylic Substitution Reactions
Paquin, J.-F.; Lautens, M. Supplement to Comprehensive Asymmetric Catalysis 2004, 73-95.

164. Addition of bifunctional organoboron reagents to strained alkenes. Carbon-carbon bond formation with Rh(I) catalysis in aqueous media
Lautens, M; Mancuso, J J. Org. Chem. 2004, 69, 3478-3487. DOI: 10.1021/jo049874k.

163. Rhodium-catalyzed asymmetric ring opening reactions of oxabicyclic alkenes: Catalyst and substrate studies leading to a mechanistic working model
Lautens, M; Fagnou, K Proc. Nat. Acad. Sci. USA 2004, 101, 5455-5460. DOI: 10.1073/pnas.0307271101.

162. Rhodium-catalyzed asymmetric ring opening of oxabicyclic alkenes with sulfur nucleophiles
Leong, P; Lautens, M J. Org. Chem. 2004, 69, 2194-2196. DOI: 10.1021/jo035730e.

161. Sequential olefin metathesis - Intramolecular asymmetric Heck reactions in the synthesis of polycycles
Lautens, M; Zunic, V Can. J. Chem. 2004, 82, 399-407. DOI: 10.1139/V03-196.

160. Scope of palladium-catalyzed alkylative ring opening
Lautens, M; Hiebert, S J. Am. Chem. Soc. 2004, 126, 1437-1447. DOI: 10.1021/ja037550s.

159. Direct vinylogous Mannich-type reactions via ring opening and rearrangement of vinyloxiranes
Lautens, M; Tayama, E; Nguyen, D Org. Lett. 2004, 6, 345-347. DOI: 10.1021/ol036153j.

2003

158. Palladium-catalyzed sequential alkylation-alkenylation reactions: New three-component coupling leading to oxacycles
Pache, S; Lautens, M Org. Lett. 2003, 5, 4827-4830. DOI: 10.1021/ol035806t.

157. Rhodium-catalyzed asymmetric ring opening reactions of oxabicyclic alkenes: Application of halide effects in the development of a general process
Lautens, M; Fagnou, K; Yang, DQ J. Am. Chem. Soc. 2003, 125, 14884-14892. DOI: 10.1021/ja034845x.

156. Synthesis of novel tetracycles via an intramolecular Heck reaction with anti-hydride elimination
Lautens, M; Fang, YQ Org. Lett. 2003, 5, 3679-3682. DOI: 10.1021/ol035354k.

155. Palladium(II) catalyst systems for the addition of boronic acids to bicyclic alkenes: New scope and reactivity
Lautens, M; Dockendorff, C Org. Lett. 2003, 5, 3695-3698. DOI: 10.1021/ol035369i.

154. Diastereoselective palladium-catalyzed formate reduction of allylic carbonates as a new entry into propionate units
Lautens, M; Paquin, JF Org. Lett. 2003, 5, 3391-3394. DOI: 10.1021/ol0350238.

153. Mild procedure for the catalytic bis(stannylation) of alkynes with hexaalkylditins
Mancuso, J; Lautens, M Org. Lett. 2003, 5, 1653-1655. DOI: 10.1021/ol034284e.

152. MgI2-mediated ring expansions of secondary methylenecyclopropyl amides
Lautens, M; Han, W; Liu, JHC J. Am. Chem. Soc. 2003, 125, 4028-4029. DOI: 10.1021/ja028967l.

151. Rhodium-catalyzed addition of arylboronic acids to alkynyl aza-heteroaromatic compounds in water
Lautens, M; Yoshida, M J. Org. Chem. 2003, 68, 762-769. DOI: 10.1021/jo0205255.

150. Transition metal-catalyzed enantioselective ring-opening reactions of oxabicyclic alkenes
Lautens, M; Fagnou, K; Hiebert, S Acc. Chem. Res. 2003, 36, 48-58. DOI: 10.1021/ar010112a.

149. Rhodium-catalyzed carbon-carbon bond forming reactions of organometallic compounds
Fagnou, K; Lautens, M Chem. Rev. 2003, 103, 169-196. DOI: 10.1021/cr020007u.

2002

148. Halide effects in transition metal catalysis
Fagnou, K; Lautens, M Angew. Chem. Int. Ed. 2002, 41, 26-47.

147. (1R*,2R*)-2-(Methylphenylamino)-1,2-dihydronaphthalen-1-ol-water (4/1)
Fagnou, K; Lautens, M; Lough, AJ Acta Cryst. 2002, E58, O1449-O1451. DOI: 10.1107/S1600536802021608.

146. Oxabicyclo[3.2.1]oct-6-enes as templates for the stereoselective synthesis of polypropionates: Total synthesis of callystatin A and C19-epi-callystatin A
Lautens, M; Stammers, TA Synthesis 2002, 1993-2012.

145. Remote electronic effects in the rhodium-catalyzed nucleophilic ring opening of oxabenzonorbornadienes
Lautens, M; Schmid, GA; Chau, A J. Org. Chem. 2002, 67, 8043-8053. DOI: 10.1021/jo025822o.

144. An expedient enantioselective route to diaminotetralins: Application in the preparation of analgesic compounds
Lautens, M; Fagnou, K; Zunic, V Org. Lett. 2002, 4, 3465-3468. DOI: 10.1021/ol026579i.

143. Benzenesulfonyl(1-hydroxy-1,2-dihydronaphthalen-2-yl)acetonitrile
Lough, AJ; Fagnou, K; Lautens, M Acta Cryst. 2002, E58, O664-O665. DOI: 10.1107/S1600536802008115.

142. Diastereoselective formation of indanes from arylboronate esters catalyzed by rhodium(I) in aqueous media
Lautens, M; Mancuso, J Org. Lett. 2002, 4, 2105-2108. DOI: 10.1021/ol0260627.

141. Divergent selectivity in MgI2-mediated ring expansions of methylenecyclopropyl amides and imides
Lautens, M; Han, WS J. Am. Chem. Soc. 2002, 124, 6312-6316. DOI: 10.1021/ja011110o.

140. (1R,2R)-2-(2-Bromophenoxy)-1,2-dihydro-naphthalen-1-ol
Fagnou, K; Lautens, M; Lough, AJ Acta Cryst. 2002, E58, o540-o541. DOI: 10.1107/S1600536802006384.

139. (1R,2R,5R,6S)-5,6-Bis(4-methoxybenzyloxymethyl)-2-(methylphenylamino)cyclohex-3-enyl 4-bromobenzoate
Lautens, M; Lough, AJ; Fagnou, K Acta Cryst. 2002, E58, o542-o543. DOI: 10.1107/S1600536802006499.

138. Palladium-catalyzed sequential alkylation-alkenylation reactions. Application to the synthesis of 2-substituted-4-benzoxepines and 2,5-disubstituted-4-benzoxepines
Lautens, M; Paquin, JF; Piguel, S J. Org. Chem. 2002, 67, 3972-3974. DOI: 10.1021/jo025730z.

137. Total synthesis of ionomycin using ring-opening strategies
Lautens, M; Colucci, JT; Hiebert, S; Smith, ND; Bouchain, G Org. Lett. 2002, 4, 1879-1882. DOI: 10.1021/ol025872f.

136. Rhodium-catalyzed asymmetric ring opening of oxabicyclic alkenes with organoboronic acids
Lautens, M; Dockendorff, C; Fagnou, K; Malicki, A Org. Lett. 2002, 4, 1311-1314. DOI: 10.1021/ol0256062.

135. Silylstannation-cyclization of 1,6-enynes using palladium(0) and palladium(II) catalysis
Lautens, M; Mancuso, J Synlett 2002, 394-398.

134. Enantioselective allylation of beta,gamma-unsaturated aldehydes generated via lewis acid induced rearrangement of 2-vinyloxiranes
Lautens, M; Maddess, ML; Sauer, EL; Ouellet, SG Org. Lett. 2002, 4, 83-86. DOI: 10.1021/o1016946a.

133. Regioselective rhodium-catalyzed addition of arylboronic acids to alkynes with a pyridine-substituted water-soluble ligand
Lautens, M; Yoshida, M Org. Lett. 2002, 4, 123-125. DOI: 10.1021/ol010261t.

2001

132. Pi-Complexes of Groups 10-8
Lautens, M. Ed. Science of Synthesis Volume 1 2001, 1111-pages.

131. Metal-Catalyzed Hydroalumination Reactions
Lautens, M.; Dahlmann, M. Catalytic Heterofunctionalization 2001, 47-72.

130. Rhodium-catalysed asymmetric ring opening of oxabicyclic alkenes with heteroatom nucleophiles
Lautens, M; Fagnou, K; Taylor, M; Rovis, T J. Organomet. Chem. 2001, 624, 259-270.

129. Novel Hydronaphthalene Compounds Prepared by a Rhodium Catalyzed Ring Opening Reaction in the Presence of a Phosphine Ligand
Fagnou, K.; Lautens, M. WO200130734-A; EP1228024-A; WO200130734-A1; AU200113206-A; NO200201968-A; BR200015117-A; EP1228024-A1; KR2002044583-A; US6525068-B1; JP2003512446-W; CN1413181-A; US2003144275-A1; ZA200203050-A; MX2002004224-A1; NZ518451-A; EP1228024-B1; US6784210-B2; DE60013471-E; AU776118-B2; EP1498406-A1; US2005014721-A1; ES2225253-T3; DE60013471-T2; MX227921-B; CN1231439-C; KR741177-B1; US7420003-B2; US2008300271-A1; MX251846-B; IL149368-A; NO328015-B1 2001, -.

128. Palladium-catalyzed sequential alkylation-alkenylation reactions and their application to the synthesis of fused aromatic rings
Lautens, M; Paquin, JF; Piguel, S; Dahlmann, M J. Org. Chem. 2001, 66, 8127-8134. DOI: 10.1021/jo0107296.

127. Effects of halide ligands and protic additives on enantioselectivity and reactivity in rhodium-catalyzed asymmetric ring-opening reactions
Lautens, M; Fagnou, K J. Am. Chem. Soc. 2001, 123, 7170-7171. DOI: 10.1021/ja010262g.

126. Mechanistic studies of the palladium-catalyzed ring opening of oxabicyclic alkenes with dialkylzinc
Lautens, M; Hiebert, S; Renaud, JL J. Am. Chem. Soc. 2001, 123, 6834-6839. DOI: 10.1021/ja010498k.

125. Rhodium-catalysed asymmetric ring opening reactions with carboxylate nucleophiles
Lautens, M; Fagnou, K Tetrahedron 2001, 57, 5067-5072.

124. Rhodium-catalyzed coupling reactions of arylboronic acids to olefins in aqueous media
Lautens, M; Roy, A; Fukuoka, K; Fagnou, K; Martin-Matute, B J. Am. Chem. Soc. 2001, 123, 5358-5359.

123. Practical synthesis of acetophenones from phenoltriflates
Garrido, F; Raeppel, S; Mann, A; Lautens, M Tetrahedron Lett. 2001, 42, 265-266.

2000

122. A new route to fused aromatic compounds by using a palladium-catalyzed alkylation - Alkenylation sequence
Lautens, M; Piguel, S Angew. Chem. Int. Ed. 2000, 39, 1045-1046.

121. Amphoteric character of 2-vinyloxiranes: Synthetic equivalents of beta,gamma-unsaturated aldehydes and a vinylogous enolate
Lautens, M; Ouellet, SG; Raeppel, S Angew. Chem. Int. Ed. 2000, 39, 4079-4082.

120. Metal-catalyzed hydrostannations
Smith, ND; Mancuso, J; Lautens, M Chem. Rev. 2000, 100, 3257-3282. DOI: 10.1021/cr9902695.

119. Rhodium-catalyzed ring opening of vinyl epoxides with alcohols and aromatic amines
Fagnou, K; Lautens, M Org. Lett. 2000, 2, 2319-2321. DOI: 10.1021/ol0060782.

118. Diastereoselective double ring closing metathesis reactions as an approach to symmetrical bicyclodienes
Lautens, M; Hughes, G; Zunic, V Can. J. Chem. 2000, 78, 868-883.

117. The use of 1,4-dichlorobut-2-ene as a synthetic equivalent of 4-bromobut-1-ene
Hughes, G; Lautens, M; Wu, JX Synlett 2000, 835-837.

116. Enantioselective ring opening of aza and oxabicyclic alkenes with dimethylzinc
Lautens, M; Hiebert, S; Renaud, JL Org. Lett. 2000, 2, 1971-1973.

115. Rhodium-catalyzed asymmetric ring opening of oxabicyclic alkenes with phenols
Lautens, M; Fagnou, K; Taylor, M Org. Lett. 2000, 2, 1677-1679.

114. Rhodium-catalyzed asymmetric alcoholysis and aminolysis of oxabenzonorbornadiene: A new enantioselective carbon-heteroatom bond forming process
Lautens, M; Fagnou, K; Rovis, T J. Am. Chem. Soc. 2000, 122, 5650-5651.

113. Formation of homoallyl stannanes via palladium-catalyzed stannylative cyclization of enynes
Lautens, M; Mancuso, J Org. Lett. 2000, 2, 671-673.

112. Palladium-catalyzed enantioselective alkylative ring opening
Lautens, M; Renaud, JL; Hiebert, S J. Am. Chem. Soc. 2000, 122, 1804-1805.

111. Synthetic studies of the formation of oxazoles and isoxazoles from N-acetoacetyl derivatives: Scope and limitations
Lautens, M; Roy, A Org. Lett. 2000, 2, 555-557.

110. Use of gamma-carboxy-alpha,beta-unsaturated aldehydes as synthetic equivalents of beta,gamma-unsaturated aldehydes in a novel stereoselective approach to diketides
Hughes, G; Lautens, M; Wen, C Org. Lett. 2000, 2, 107-110.

1999

109. Allylic Substitution Reaction
Pfaltz, Andreas; Lautens, Mark Comprehensive Asymmetric Catalysis I-III 1999, 2, 833-884.

108. Hydroalumination of Carbon-Carbon Double Bonds
Jacobsen, Eric N.; Pfaltz, Andreas; Yamamoto, Hisashi Comprehensive Asymmetric Catalysis I-III 1999, 1, 337-348.

107. Diastereoselective ring closing metathesis reactions: Synthesis of bicyclic diallylic alcohols and ethers
Lautens, M; Hughes, G Angew. Chem. Int. Ed. 1999, 38, 129-131.

106. Cerium(III) chloride promoted opening of [3.2.1] oxabicycles with methyllithium
Lautens, M; de Frutos, O; Stammers, TA Tetrahedron Lett. 1999, 40, 8317-8321.

105. Total synthesis of bryostatin 2
Evans, DA; Carter, PH; Carreira, EM; Charette, AB; Prunet, JA; Lautens, M J. Am. Chem. Soc. 1999, 121, 7540-7552.

104. Selective functionalization of 1,2-dihydronaphthalenols leads to a concise, stereoselective synthesis of sertraline.
Lautens, M; Rovis, T Tetrahedron 1999, 55, 8967-8976.

1998

103. Asymmetric synthesis of bryostatin 2
Evans, DA; Carter, PH; Carreira, EM; Prunet, JA; Charette, AB; Lautens, M Angew. Chem. Int. Ed. 1998, 37, 2354-2359.

102. Mammalian lignans inhibit the growth of estrogen-independent human colon tumor cells
Sung, MK; Lautens, M; Thompson, LU ANTICANCER RESEARCH 1998, 18, 1405-1408.

101. Metal catalyzed hydrometalations and their applications in synthesis
Lautens, M; Rovis, T; Smith, ND; Ostrovsky, D PURE AND APPLIED CHEMISTRY 1998, 70, 1059-1064.

100. Metathesis copolymerization of phenylacetylene with cycloolefins catalysed by WCl6-n-Bu4Sn
Misumi, Y; Maekawa, T; Masuda, T; Higashimura, T; Lautens, M POLYMER 1998, 39, 1663-1667.

99. The utility of the homo Diels-Alder reaction in the synthesis of natural product skeletons: A cycloaddition-fragmentation-cyclization sequence to diquinanes and triquinanes
Lautens, M; Blackwell, J Synthesis 1998, 537-546.

98. The effect of the acidifying group on the regioselectivity of the base-induced ring opening of hetero-oxabicyclic [3.2.1] and [3.3.1] systems
Lautens, M; Fillion, E; Sampat, M Tetrahedron Lett. 1998, 39, 1501-1504.

97. Scope of the nickel catalyzed asymmetric reductive ring opening reaction. Synthesis of enantiomerically enriched cyclohexenols.
Lautens, M; Rovis, T Tetrahedron 1998, 54, 1107-1116.

96. Exploring the reactivity of dioxacyclic compounds as a route to polysubstituted decalins and fused polycycles
Lautens, M; Fillion, E J. Org. Chem. 1998, 63, 647-656. DOI: .

95. Transition Metal-Catalyzed Cycloaddition Reactions of Bicyclo[2.2.1]hepta-2,5-dienes (Norbornadienes)
Lautens, M.; Tam, W. Metal-Mediated Organic Chemistry 1998, 6, 49-101.

1997

94. Palladium catalyzed hydrostannation-cyclization of 1,6-diynes. Generation of 1,2-dialkylidenecyclopentanes with a tributylstannane moiety
Lautens, M; Smith, ND; Ostrovsky, D J. Org. Chem. 1997, 62, 8970-8971.

93. A new route to the enantioselective synthesis of cycloheptenols. Temperature effects in the asymmetric reductive ring opening of [3.2.1] oxabicycloalkenes
Lautens, M; Rovis, T J. Am. Chem. Soc. 1997, 119, 11090-11091.

92. Base-induced ring opening of aza- and thiaoxa[3.2.1] and -[3.3.1]bicycles as an enantioselective approach to azepines, thiepines, and thiocines
Lautens, M; Fillion, E; Sampat, M J. Org. Chem. 1997, 62, 7080-7081.

91. Regioselective hydrostannation of allenes catalyzed by Pd(OH)(2)/C
Lautens, M; Ostrovsky, D; Tao, B Tetrahedron Lett. 1997, 38, 6343-6346.

90. The crystal structure and absolute configuration of exo-R-c,S-s)-(-)-8-p-tolylsulfinyltetracyclo[4.3.0.0(2,4).0(3,7)]nonane
Edwards, LG; Lautens, M; Lough, AJ JOURNAL OF CHEMICAL CRYSTALLOGRAPHY 1997, 27, 471-474.

89. General strategy toward the tetrahydronaphthalene skeleton. An expedient total synthesis of sertraline
Lautens, M; Rovis, T J. Org. Chem. 1997, 62, 5246-5247.

88. Synthesis of cyclohexenols and cycloheptenols via the regioselective reductive ring opening of oxabicyclic compounds
Lautens, M; Ma, SH; Chiu, P J. Am. Chem. Soc. 1997, 119, 6478-6487.

87. (cis-1-cyclophexyl-6-methylene-3,5,6,6a-tetrahydro-1H-cyclopenta[c]furan-4-yl)methyl 3,5-dinitrobenzoate
Lautens, M; Lough, AJ; Ren, Y ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 1997, 53, 936-938.

86. An expedient route for the stereoselective construction of bridged polyheterocyclic ring systems using the tandem ''pincer'' Diels-Alder reaction
Lautens, M; Fillion, E J. Org. Chem. 1997, 62, 4418-4427.

85. Synthesis and reactions of 1,2-disubstituted methylenecyclopropanes prepared via intramolecular cyclopropanation of allenic diazoacetates.
Lautens, M; Meyer, C; vanOeveren, A Tetrahedron Lett. 1997, 38, 3833-3836.

84. Synthesis of highly functionalized diquinanes by the regio- and stereoselective cleavage of homo-Diels-Alder cycloadducts
Lautens, M; Tam, W; Blackwell, J J. Am. Chem. Soc. 1997, 119, 623-624.

83. Using Ring-Opening Reactions of Oxabicyclic Compounds as a Strategy in Organic Synthesis
Lautens, M.; Chiu, P. Topics in Current Chemistry 1997, 190, 1-85.

1996

82. Allyl 1,1-bimetallic species: their preparation and reactivity profile
Lautens, Mark; Ben, Robert N.; Delanghe, Patrick H. M. Tetrahedron 1996, 52, 7221-7234.

81. The structures of two [2 pi+2 pi] cycloaddition adducts
Edwards, LG; Lautens, M; Lough, AJ ZEITSCHRIFT FUR KRISTALLOGRAPHIE 1996, 211, 919-923.

80. New strategy for the stereocontrolled construction of decalins and fused polycycles via a tandem Diels-Alder ring-opening sequence
Lautens, M; Fillion, E J. Org. Chem. 1996, 61, 7994-7995.

79. Diastereoselective intermolecular [4+3] cycloadditions via an extended transition state: A route to enantiomerically enriched cycloadducts
Lautens, M; Aspiotis, R; Colucci, J J. Am. Chem. Soc. 1996, 118, 10930-10931.

78. Palladium-catalyzed intramolecular [3+2] cycloadditions of methylenecyclopropanes with alkenes: Diastereomeric methylenecyclopropanes exhibit complementary facial selectivity
Lautens, M; Ren, Y J. Am. Chem. Soc. 1996, 118, 10668-10669.

77. Ring opening in the hydrostannation of methylenecyclopropanes: Effect of the catalyst and substrate
Lautens, M; Meyer, C; Lorenz, A J. Am. Chem. Soc. 1996, 118, 10676-10677.

76. Nickel-catalyzed addition of grignard reagents to oxabicyclic compounds. Ring-opening reactions with previously unreactive substrates and nucleophiles
Lautens, M; Ma, SH J. Org. Chem. 1996, 61, 7246-7247.

75. Transition metal catalyzed stereospecific intramolecular [3+2] cycloadditions of methylenecyclopropanes with alkynes
Lautens, M; Ren, Y J. Am. Chem. Soc. 1996, 118, 9597-9605.

74. Heterogeneous palladium-catalyzed regioselective hydrostannation of alkenes
Lautens, M; Kumanovic, S; Meyer, C Angew. Chem. Int. Ed. IN ENGLISH 1996, 35, 1329-1330.

73. Allyl 1,1-bimetallic species: Their preparation and reactivity profile
Lautens, M; Ben, RN; Delanghe, PHM Tetrahedron 1996, 52, 7221-7234.

72. Chlorotrimethylsilane as an activating reagent in the samarium-promoted cyclopropanation of allylic and alpha-allenic alcohols
Lautens, M; Ren, Y J. Org. Chem. 1996, 61, 2210-2214.

71. Reductive and base-induced cleavage reactions of oxabicyclic compounds
Lautens, M; Ma, SH Tetrahedron Lett. 1996, 37, 1727-1730.

70. Regioselective palladium-catalyzed hydrostannylation of unsymmetrical oxabicyclic alkenes
Lautens, M; Klute, W Angew. Chem. Int. Ed. IN ENGLISH 1996, 35, 442-445.

69. Transition metal-mediated cycloaddition reactions
Lautens, M; Klute, W; Tam, W Chem. Rev. 1996, 96, 49-92.

1995

68. A HIGHLY SUBSTITUTED TRANS-FUSED BICYCLO-[5.3.0]DECENE
KUMANOVIC, S; LAUTENS, M; LOUGH, AJ ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 1995, 51, 2370-2372.

67. NICKEL-CATALYZED [2-PI+2-PI+2-PI] (HOMO-DIELS-ALDER) AND [2-PI+2-PI] CYCLOADDITIONS OF BICYCLO[2.2.1]HEPTA-2,5-DIENES
LAUTENS, M; EDWARDS, LG; TAM, W; LOUGH, AJ J. Am. Chem. Soc. 1995, 117, 10276-10291.

66. AN UNUSUAL TRANS-FUSED CYCLOPENTANE RING-SYSTEM AT 158 K
LAUTENS, M; LOUGH, AJ; TAM, W ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 1995, 51, 1944-1946.

65. 1994 MERCK-FROSST-AWARD-LECTURE - NEW STRATEGIES FOR THE STEREOSELECTIVE SYNTHESIS OF NATURAL AND UNNATURAL PRODUCTS VIA ORGANOMETALLIC REAGENTS AND CATALYSTS
LAUTENS, M; REN, Y; DELANGHE, P; CHIU, P; MA, SH; COLUCCI, J Can. J. Chem. 1995, 73, 1251-1257.

64. COBALT-CATALYZED [2-PI+2-PI+2-PI] (HOMO DIELS-ALDER) AND [2-PI+2-PI+4-PI] CYCLOADDITIONS OF BICYCLO[2.2.1]HEPTA-2,5-DIENES
LAUTENS, M; TAM, W; LAUTENS, JC; EDWARDS, LG; CRUDDEN, CM; SMITH, AC J. Am. Chem. Soc. 1995, 117, 6863-6879.

63. STUDIES IN THE TRANSMETALATION OF CYCLOPROPYL, VINYL, AND EPOXY STANNANES
LAUTENS, M; DELANGHE, PHM; GOH, JB; ZHANG, CH J. Org. Chem. 1995, 60, 4213-4227.

62. ASYMMETRIC-SYNTHESIS OF THE LACTONE MOIETY OF MEVINIC ACID
LAUTENS, M; MA, SH; YEE, A Tetrahedron Lett. 1995, 36, 4185-4188.

61. PRODUCT OF AN S(N)2' RING-OPENING REACTION, (1R-ASTERISK,2R-ASTERISK,3R-ASTERISK,4R-ASTERISK,7R-ASTERISK)-2,4,7-TRIMETHYLCYCLOHEPT-5-ENE-1,3-DIOL
COLUCCI, J; GAJDA, C; LAUTENS, M; LOUGH, AJ ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 1995, 51, 912-914.

60. DIASTEREOSELECTIVITY IN THE CYCLOPROPANATION OF 3,3-BIMETALLIC ALLYLIC ALCOHOLS - PREPARATION OF DIASTEREOMERIC CYCLOPROPYL CARBINOLS VIA A SIMPLE OXIDATION-REDUCTION SEQUENCE
LAUTENS, M; DELANGHE, PHM J. Org. Chem. 1995, 60, 2474-2487.

59. 2 HIGHLY SUBSTITUTED METHYLENECYDOPROPANES
DELANGHE, PHM; LAUTENS, M; LOUGH, AJ ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 1995, 51, 700-703.

58. 4-[(TRIMETHYLSILYL)METHYL]TETRACYCLO[5.4.0.0(6.10).0(9,11)]UNDEC-3-YL 3,5-DINITROBENZOATE
LAUTENS, M; LOUGH, AJ; TAM, W ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 1995, 51, 471-473.

57. A NEW STRATEGY TO BICYCLO[5.3.0]DECENES VIA ANIONIC INTRAMOLECULAR RING-OPENING OF OXABICYCLO[3.2.1] COMPOUNDS
LAUTENS, M; KUMANOVIC, S J. Am. Chem. Soc. 1995, 117, 1954-1964.

56. NICKEL-CATALYZED HYDROALUMINATION OF OXABICYCLIC ALKENES - LIGAND EFFECTS ON THE REGIOSELECTIVITY AND ENANTIOSELECTIVITY
LAUTENS, M; CHIU, P; MA, SH; ROVIS, T J. Am. Chem. Soc. 1995, 117, 532-533.

1994

55. EFFECT OF THE SUBSTITUENTS ON THE DIASTEREOSELECTIVITY IN THE REDUCTION OF CYCLOPROPYL KETONES
DELANGHE, PHM; LAUTENS, M Tetrahedron Lett. 1994, 35, 9513-9516.

54. EXPLORING THE REACTIVITY OF ALKENES BEARING SILICON AND/OR TIN IN THE HYDROXYL-DIRECTED HYDROGENATION - A DIASTEREOSELECTIVE SYNTHESIS OF HETEROBIMETALLIC COMPOUNDS
LAUTENS, M; ZHANG, CH; GOH, BJ; CRUDDEN, CM; JOHNSON, MJA J. Org. Chem. 1994, 59, 6208-6222.

53. STUDIES IN THE DIRECTED CYCLOPROPANATION OF ALPHA-ALLENIC ALCOHOLS
LAUTENS, M; DELANGHE, PHM J. Am. Chem. Soc. 1994, 116, 8526-8535.

52. STEREOCHEMICAL CONTROL IN METAL-CATALYZED [3+2] CYCLOADDITIONS OF METHYLENECYCLOPROPANES
LAUTENS, M; REN, Y; DELANGHE, PHM J. Am. Chem. Soc. 1994, 116, 8821-8822.

51. STEREOSELECTIVITY IN THE HOMO-DIELS-ALDER REACTION - EFFECT OF A REMOTE 7-SUBSTITUENT ON NICKEL-CATALYZED CYCLOADDITIONS
LAUTENS, M; TAM, W; EDWARDS, LG JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 1994, 2143-2150.

50. PD-CATALYZED CYCLOISOMERIZATION TO 1,2-DIALKYLIDENECYCLOALKANES .1.
TROST, BM; TANOURY, GJ; LAUTENS, M; CHAN, C; MACPHERSON, DT J. Am. Chem. Soc. 1994, 116, 4255-4267.

49. A REGIOSELECTIVE PALLADIUM-CATALYZED REDUCTION OF 3,3-HETEROBIMETALATED ALLYLIC ACETATES - SYNTHESIS AND REACTIVITY OF ALLYLIC BIMETALLIC COMPOUNDS
LAUTENS, M; DELANGHE, PHM Angew. Chem. Int. Ed. 1994, 33, 2448-2450.

1993

48. REGIOSELECTIVE CYCLOPROPANATION OF ALPHA-ALLENIC ALCOHOLS - AN EFFICIENT ROUTE TO ALKYLIDENECYCLOPROPANES
LAUTENS, M; DELANGHE, PHM J. Org. Chem. 1993, 58, 5037-5039.

47. ENANTIOSELECTIVE COBALT-CATALYZED [4-PI+2-PI+2-PI] CYCLOADDITIONS
LAUTENS, M; TAM, W; SOOD, C J. Org. Chem. 1993, 58, 4513-4515.

46. STUDIES IN THE ASYMMETRIC RING-OPENING OF AN OXABICYCLIC COMPOUND - CATALYTIC ASYMMETRIC INDUCTION USING (-)-SPARTEINE
LAUTENS, M; GAJDA, C; CHIU, P JOURNAL OF THE CHEMICAL SOCIETY-Chem. Commun. 1993, 1193-1194.

45. AN EFFICIENT SYNTHESIS OF HIGHLY SUBSTITUTED 1,3-CYCLOHEXADIENES FROM OXABICYCLO[3.2.1]OCTENES - SOLVENT EFFECTS IN THE RING-OPENING REACTION
LAUTENS, M; GAJDA, C Tetrahedron Lett. 1993, 34, 4591-4594.

44. RING-OPENING REACTIONS OF OXABICYCLIC COMPOUNDS AS A ROUTE TO CYCLIC AND ACYCLIC COMPOUNDS WITH MULTIPLE STEREOCENTERS
LAUTENS, M Synlett 1993, 177-185.

43. REDUCTIVE RING-OPENING OF OXABICYCLIC COMPOUNDS WITH DIISOBUTYLALUMINUM HYDRIDE - APPLICATION TO THE SYNTHESIS OF THE C-17-C-23 SUBUNIT OF IONOMYCIN
LAUTENS, M; CHIU, P; COLUCCI, JT Angew. Chem. Int. Ed. IN ENGLISH 1993, 32, 281-283.

42. SYNTHESIS AND CHARACTERIZATION OF THE RING-OPENED COPOLYMERS OF DELTACYCLENE, 5-SILOXYDELTACYCLENE, AND NORBORNENE
LAUTENS, M; ABDELAZIZ, AS; CRUDDEN, CM JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 1993, 31, 569-574.

41. REGIOSELECTIVE NUCLEOPHILIC RING-OPENING OF OXABICYCLIC COMPOUNDS
LAUTENS, M; CHIU, P Tetrahedron Lett. 1993, 34, 773-776.

1992

40. NEW METHODS FOR THE CONTROL OF MULTIPLE STEREOCENTERS
LAUTENS, M PURE AND APPLIED CHEMISTRY 1992, 64, 1873-1882.

39. 1,4-SILYL MIGRATION REACTIONS - APPLICABILITY TO ALKYLPROPYLSILANES, VINYLPROPYLSILANES, AND CYCLOPROPYLSILANES
LAUTENS, M; DELANGHE, PHM; GOH, JB; ZHANG, CH J. Org. Chem. 1992, 57, 3270-3272.

38. ASYMMETRIC HYDROFORMYLATION OF DELTACYCLENE
KOLLAR, L; WADA, T; LAUTENS, M Tetrahedron-ASYMMETRY 1992, 3, 1011-1014.

37. AN EFFICIENT SYNTHESIS OF 1,3-CYCLOHEXADIENES FROM OXABICYCLO[2.2.1.]HEPTENES VIA TANDEM RING-OPENING PETERSON ELIMINATION-REACTIONS
LAUTENS, M; MA, SH; BELTER, RK; CHIU, P; LESCHZINER, A J. Org. Chem. 1992, 57, 4065-4066.

36. DIASTEREOSELECTIVITY IN THE HYDROXYL-DIRECTED CYCLOPROPANATION OF VINYLORGANOMETALLIC COMPOUNDS
LAUTENS, M; DELANGHE, PHM J. Org. Chem. 1992, 57, 798-800.

35. THE EFFECT OF REMOTE OXYGENS ON THE RING-OPENING REACTIONS OF OXABICYCLIC COMPOUNDS WITH ORGANOLITHIUM REAGENTS - SYNTHESIS OF THE C21-C27 SEGMENT OF RIFAMYCIN-S
LAUTENS, M; BELTER, RK Tetrahedron Lett. 1992, 33, 2617-2620.

34. THE HYDROXYL-DIRECTED HYDROGENATION OF VINYLSTANNANES AND SILANES - A HIGHLY DIASTEREOSELECTIVE ROUTE TO BETA-STANNYL AND BETA-SILYL ALCOHOLS
LAUTENS, M; ZHANG, CH; CRUDDEN, CM Angew. Chem. Int. Ed. IN ENGLISH 1992, 31, 232-234.

33. SILACUPRATION OF OXABICYCLIC COMPOUNDS - AN INTERRUPTED RING-OPENING REACTION
LAUTENS, M; BELTER, RK; LOUGH, AJ J. Org. Chem. 1992, 57, 422-424.

32. COBALT-CATALYZED INTRAMOLECULAR HOMO DIELS-ALDER REACTIONS
LAUTENS, M; TAM, W; EDWARDS, LG J. Org. Chem. 1992, 57, 8-9.

1991

31. THE REDUCTIVE RING-OPENING OF OXABICYCLIC COMPOUNDS
LAUTENS, M; CHIU, P Tetrahedron Lett. 1991, 32, 4827-4830.

30. REGIOCHEMICAL CONTROL IN THE HOMO-DIELS-ALDER REACTION - SUBSTITUENT EFFECTS
LAUTENS, M; EDWARDS, LG J. Org. Chem. 1991, 56, 3761-3763.

29. STRUCTURE OF THE MOSHERS ESTER DERIVATIVE OF 5-PHENYLDELTACYCLENE
LAUTENS, JC; LAUTENS, M; LOUGH, AJ ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 1991, 47, 2725-2727.

28. PREPARATION AND RING-OPENING METATHESIS POLYMERIZATIONS OF 5-SILOXYDELTACYCLENE AND DELTACYCLENE USING THE SCHROCK MOLYBDENUM ALKYLIDENE CATALYST
LAUTENS, M; CRUDDEN, CM; ABDELAZIZ, AS; WADA, T MACROMOLECULES 1991, 24, 1425-1427.

27. ANNULATION VIA ALKYLATION ALDER ENE CYCLIZATIONS - PD-CATALYZED CYCLOISOMERIZATION OF 1,6-ENYNES
TROST, BM; LAUTENS, M; CHAN, C; JEBARATNAM, DJ; MUELLER, T J. Am. Chem. Soc. 1991, 113, 636-644.

26. TRANS-4-TERT-BUTYL-3-HYDROXY-5-CYCLOHEPTEN-1-ONE (2) AND TRANS-6-TERT-BUTYL-3-HYDROXY-2,7-DIMETHYL-4-CYCLOHEPTEN-1-ONE (5)
ABDELAZIZ, AS; LAUTENS, M; LOUGH, AJ ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 1991, 47, 1047-1050.

1990

25. A ROUTE TO 1,1-DIORGANOMETALLIC SPECIES VIA THE CLAISEN REARRANGEMENT OF FUNCTIONALIZED GAMMA-HYDROXYVINYLSTANNANES
LAUTENS, M; HUBOUX, AH; CHIN, B; DOWNER, J Tetrahedron Lett. 1990, 31, 5829-5832.

24. OPENING OF OXABICYCLO[3.2.1]OCTENES WITH ORGANOLITHIUM REAGENTS - A ROUTE TO CYCLIC AND ACYCLIC COMPOUNDS WITH HIGH STEREOCONTROL
LAUTENS, M; ABDELAZIZ, AS; LOUGH, A J. Org. Chem. 1990, 55, 5305-5306.

23. PREPARATION OF CYCLOHEXENYL DERIVATIVES BY THE RING-OPENING REACTIONS OF OXABICYCLO[2.2.1] COMPOUNDS WITH CUPRATES
LAUTENS, M; SMITH, AC; ABDELAZIZ, AS; HUBOUX, AH Tetrahedron Lett. 1990, 31, 3253-3256.

22. A ROUTE TO THE PREPARATION OF GAMMA-HYDROXYVINYLSTANNANES
LAUTENS, M; HUBOUX, AH Tetrahedron Lett. 1990, 31, 3105-3108.

21. CATALYTIC ASYMMETRIC INDUCTION IN THE HOMO DIELS-ALDER REACTION
LAUTENS, M; LAUTENS, JC; SMITH, AC J. Am. Chem. Soc. 1990, 112, 5627-5628.

20. SYNTHESIS AND EPOXIDATION OF CIS-ENRICHED POLYDELTACYCLENE
LAUTENS, M; ABDELAZIZ, AS; SCHMIDT, G MACROMOLECULES 1990, 23, 2819-2821.

1989

19. RING-OPENING REACTIONS OF AN OXABICYCLIC COMPOUND WITH CUPRATES
LAUTENS, M; DIFELICE, C; HUBOUX, A Tetrahedron Lett. 1989, 30, 6817-6820.

18. STEREOSELECTIVITY IN THE HOMO DIELS-ALDER REACTION
LAUTENS, M; EDWARDS, LG Tetrahedron Lett. 1989, 30, 6813-6816.

17. SCOPE OF THE COBALT-CATALYZED [2+2+2] HOMO-DIELS-ALDER REACTION
LAUTENS, M; CRUDDEN, CM Organometallics 1989, 8, 2733-2735.

16. RING-OPENING METATHESIS POLYMERIZATION OF DELTACYCLENE VIA A RUTHENIUM CATALYST
LAUTENS, M; ABDELAZIZ, AS; REIBEL, J MACROMOLECULES 1989, 22, 4132-4134.

15. RING-OPENING REACTIONS OF DELTACYCLENE EPOXIDES
LAUTENS, M; CRUDDEN, CM Tetrahedron Lett. 1989, 30, 4803-4806.

1987

14. REGIOCHEMICAL DIVERSITY IN ALLYLIC ALKYLATIONS VIA MOLYBDENUM CATALYSTS
TROST, BM; LAUTENS, M Tetrahedron 1987, 43, 4817-4840.

13. CHEMOSELECTIVITY AND STEREOCONTROL IN MOLYBDENUM-CATALYZED ALLYLIC ALKYLATIONS
TROST, BM; LAUTENS, M J. Am. Chem. Soc. 1987, 109, 1469-1478.

1985

12. OXIDATION OF OLEFINS BY PALLADIUM(II) .10. PRODUCTS OF THE REACTION OF PDCL42- WITH ALLYL ALCOHOL IN AQUEOUS-SOLUTION
ZAW, K; LAUTENS, M; HENRY, PM Organometallics 1985, 4, 1286-1291.

11. AN UNUSUAL DICHOTOMY IN THE REGIOSELECTIVITY OF A METAL-CATALYZED VERSUS THERMAL ENE REACTION
TROST, BM; LAUTENS, M Tetrahedron Lett. 1985, 26, 4887-4890.

10. CYCLIZATION VIA ISOMERIZATION - A PALLADIUM(2+)-CATALYZED CARBOCYCLIZATION OF 1,6-ENYNES TO 1,3-DIENES AND 1,4-DIENES
TROST, BM; LAUTENS, M J. Am. Chem. Soc. 1985, 107, 1781-1783.

1984

9. TANDEM ALKYLATION CYCLO-ADDITIONS - CONTROL BY TRANSITION-METAL TEMPLATES
TROST, BM; LAUTENS, M; HUNG, MH; CARMICHAEL, CS J. Am. Chem. Soc. 1984, 106, 7641-7643.

1983

8. Reshuffling the Rules of Selectivity: Molybdenum Catalysts Lead the Way
Trost, B.M.; Lautens, M. Industrial Chemical News 1983, 4, 1-4.

7. MOLYBDENUM CATALYZED ELIMINATIONS OF ALLYLIC ACETATES - NEW DIENE SYNTHESIS
TROST, BM; LAUTENS, M; PETERSON, B Tetrahedron Lett. 1983, 24, 4525-4528.

6. TRIS(TRIMETHYLSILYL)ALUMINUM AND TRANSITION-METAL CATALYSTS - SILYLATION OF ALLYL ACETATES
TROST, BM; YOSHIDA, J; LAUTENS, M J. Am. Chem. Soc. 1983, 105, 4494-4496.

5. REGIOCHEMICAL CONTROL IN THE MOLYBDENUM-CATALYZED REACTIONS OF TRIMETHYLSILYL-SUBSTITUTED AND ESTER-SUBSTITUTED ALLYLIC ACETATES
TROST, BM; LAUTENS, M Organometallics 1983, 2, 1687-1689.

4. NOVEL PARALLEL PATH MECHANISM FOR THE OXIDATION OF ALLYL ALCOHOL BY AQUEOUS PALLADIUM(II) CHLORIDE
ZAW, K; LAUTENS, M; HENRY, PM Organometallics 1983, 2, 197-199.

3. ON THE STEREOSELECTIVITY AND REGIOSELECTIVITY OF MOLYBDENUM-CATALYZED ALLYLIC ALKYLATIONS - STEREOCONTROLLED APPROACH TO QUATERNARY CARBONS AND TANDEM ALKYLATION CYCLOADDITION
TROST, BM; LAUTENS, M J. Am. Chem. Soc. 1983, 105, 3343-3344.

1982

2. MOLYBDENUM CATALYSTS FOR ALLYLIC ALKYLATION
TROST, BM; LAUTENS, M J. Am. Chem. Soc. 1982, 104, 5543-5545.

1981

1. Synthesis of an isomer of the germacranolide isoaristolactone
LANGE, GL; SO, S; LAUTENS, M; LOHR, K Tetrahedron Lett. 1981, 22, 311-312.