
@article {147,
	title = {Dehydrative glycosidations of 2-deoxysugar derivatives catalyzed by an arylboronic ester},
	journal = {Carbohydrate Research},
	volume = {470},
	year = {2018},
	month = {2018/12/01/},
	pages = {42 - 49},
	abstract = {<p>An N-methylpyridinium-4-boronic ester acts as a catalyst for dehydrative glycosidations of 2-deoxy sugar-derived hemiacetals. The catalytic protocol is tolerant of functionalized acceptors, including alcohols bearing isopropylidene ketal, tert-butyl carbamate or benzyl carbamate groups. The results demonstrate that organoboron-catalyzed substitution reactions of alcohols, which have previously been conducted on π-activated (benzylic, allylic or propargylic) substrates, can also be used to achieve C{\textendash}O bond formation from carbohydrate-derived hemiacetals.</p>},
	keywords = {2-Deoxyglycoside, Boronic acid, Catalysis, Glycosidation},
	isbn = {0008-6215},
	url = {http://www.sciencedirect.com/science/article/pii/S0008621518304579},
	author = {Manhas, Sanjay and Taylor, Mark S.}
}
