
@article {240,
	title = {On the mechanism of carboxylate elimination from carbohydrate monoester-derived radicals},
	journal = {Organic \& Biomolecular Chemistry},
	volume = {22},
	year = {2024},
	month = {2024},
	pages = {3225{\textendash}3229},
	abstract = {A computational study of the mechanism of hydrogen atom transfer-induced carboxylate elimination from monoacylated 1,2-diol groups in pyranosides is presented. A comprehensive analysis of the 1,2-migration, elimination and fragmentation pathways reveals that concerted elimination via a 7-membered, hydrogen-bonded transition state is favored. Relative rates of elimination inferred from an intramolecular competition experiment are consistent with the trends obtained from the calculations.},
	isbn = {1477-0520},
	url = {http://dx.doi.org/10.1039/D4OB00241E},
	author = {Turner, Julia A. and Zipse, Hendrik and Taylor, Mark S.}
}
